Among the following complexes, the one that can exhibit optical activity is

1.  ${\left[{\mathrm{CoCl}}_6\right]}^{3-}$

2.  ${\left[\mathrm{Co}\left(\mathrm{en}\right){\mathrm{CI}}_4\right]}^{-}$

3.  $\mathrm{cis}-{\left[\mathrm{Co}{\left(\mathrm{en}\right)}_2{\mathrm{Cl}}_2\right]}^{+}$

4.  trans-${\left[\mathrm{Co}{\left(\mathrm{en}\right)}_2{\mathrm{Cl}}_2\right]}^{+}$

2.335 g of compound X (empirical formal ${\mathrm{CoH}}_{12}{\mathrm{N}}_4{\mathrm{Cl}}_3$) upon treatment with excess ${\mathrm{AgNO}}_3$ solution produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X, respectively are

[Given Atomic mass: Co = 59, Cl = 35.5, Ag = 108]

1.  3, 6

2.  3,  4

3.  2,  4

4.  4, 3

 $$\begin{gathered} \mathrm{Among}<mspace\; width="1em"></mspace>\left(\mathrm{i}\right)<mspace\; width="1em"></mspace>{\left[\mathrm{Cr}{\left(\mathrm{en}\right)}_3\right]}^{3+},<mspace\; width="1em"></mspace>\left(\mathrm{ii}\right)<mspace\; width="1em"></mspace>\mathrm{trans}-{\left[\mathrm{Cr}{\left(\mathrm{en}\right)}_2{\mathrm{Cl}}_2\right]}^{+},<mspace\; width="1em"></mspace> \\ \left(\mathrm{iii}\right)<mspace\; width="1em"></mspace>\mathrm{cis}-{\left[\mathrm{Cr}{\left(\mathrm{en}\right)}_2{\mathrm{Cl}}_2\right]}^{+},<mspace\; width="1em"></mspace>\left(\mathrm{iv}\right)<mspace\; width="1em"></mspace>{\left[\mathrm{Co}{\left({\mathrm{NH}}_3\right)}_4\mathrm{Cl}\right]}^{+},<mspace\; width="1em"></mspace>\mathrm{the}<mspace\; width="1em"></mspace>\mathrm{optically}<mspace\; width="1em"></mspace>\mathrm{active} \\ \mathrm{complexes}<mspace\; width="1em"></mspace>\mathrm{are} \end{gathered}$$

1.  (i) and (ii)

2.  (i) and (iii)

3.  (ii) and (iii)

4.  (ii) and (iv)

Which of the following coordination complexes can exist as facial (fac) and meridional (mer) isomers?

1.  $\left[\mathrm{Co}{\left({\mathrm{NO}}_2\right)}_3{\left({\mathrm{NH}}_3\right)}_3\right]$

2.  ${\mathrm{K}}_3\left[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6\right]$

3.  $\left[\mathrm{Co}{\left({\mathrm{H}}_2\mathrm{O}\right)}_2{\left({\mathrm{NH}}_3\right)}_4\right]{\mathrm{Cl}}_3$

4.  $\left[\mathrm{CoCl}{\left({\mathrm{NH}}_3\right)}_5\right]\mathrm{Cl}$

Hybridization and geometry of ${\left[\mathrm{Ni}{\left(\mathrm{CN}\right)}_4\right]}^{2-}$ are

1.  $s{p}^{2}d$ and tetrahedral

2.  $s{p}^3$ and square planar

3.  $s{p}^3$ and tetrahedral

4.  $ds{p}^2$ and square planar

The total number of geometrical isomers possible for an octahedral complex of this type $\left[{\mathrm{MA}}_2{\mathrm{B}}_2{\mathrm{C}}_2\right]$ is 

(M = transition metal; A, B and C are monodentate ligands)

1.  3

2.  4

3.  5

4.  6

The IUPAC name of $\left[\mathrm{Co}\left(\mathrm{ONO}\right){\left({\mathrm{NH}}_3\right)}_5\right]{\mathrm{Cl}}_2$ is:

1. Pentamminenitro-O-cobalt(II)chloride

2. Pentamminenitroso-O-cobalt(III)chloride  

3. Pentaamminenitrito-O-cobalt(III) chloride

4. Pentammineoxo-nitrocobalt(III)chloride

The metal carbonyl which is paramagnetic is

1. $\mathrm{Ni}{\left(\mathrm{CO}\right)}_4$

2. $\mathrm{V}{\left(\mathrm{CO}\right)}_6$

3. $\mathrm{Cr}{\left(\mathrm{CO}\right)}_6$

4. $\mathrm{Fe}{\left(\mathrm{CO}\right)}_5$