Choose the correct statement regarding bonding in FeCl₃ at high temperature?

(I) It contains 2c-2e- bond

(II) It contains 3c-2e- bond

(III) It contains a co-ordinate bond

1. (I), (II)

2. (I), (III)

3. (II), (III)

4. (I), (II) & (III)

 Given lanthanoid ions ,the tendency to form the complexes is highest for:

1. Ce⁺³

2. Pm⁺²

3. Lu⁺³

4. Eu⁺²

The fusion of chromite ore (FeCr₂O₄) with Na₂CO₃ in air gives a yellow solution upon the addition of water. Subsequent treatment with H₂SO₄ produces an orange solution.

The yellow and orange colours, respectively, are due to the formation of:

1. Na₂CrO₄ and Na₂Cr₂O₇

2. Cr(OH)₃ and Na₂Cr₂O₇

3. Cr₂(CO₃)₃ and Fe₂(SO₄)₃

4. Cr(OH)₃ and Na₂CrO₄

Which of the following statements is false? 

The incorrect statement about Re-Re bonding in [Re₂X₈]^2- is

(1) Re-Re bond length is abnormally short

(2) Re-Re bond is comprised of one $\mathrm{\sigma },<mspace\; width="1em"></mspace>\mathrm{two}<mspace\; width="1em"></mspace>\mathrm{\pi }<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>\mathrm{one}<mspace\; width="1em"></mspace>\mathrm{\delta }<mspace\; width="1em"></mspace>\mathrm{bond}$

(3) If Re-Re bond points along z-axis, then square planar ReX₄ unit will use s, p_x, p_y and d_x²-y² orbitals for the formation of four Re-X $\mathrm{\sigma }$ bonds

(4) d_xy orbitals will overlap to form $\mathrm{\delta }$-bond

While Fe³⁺ is stable, Mn³⁺ is not stable in acidic solution because

1. O₂ oxidises Mn²⁺ to Mn³⁺

2. O₂ oxidises both Mn⁺² to Mn⁺³ and Fe²⁺ to Fe³⁺

3. Fe³⁺ oxidises H₂O to O₂

4. Mn³⁺ oxidised H₂O to O₂

Dimethyl glyoxime in a suitable solvent was refluxed for 10 minutes with pure pieces of nickel sheet, it will result in

1. Red precipitate

2. Blue precipitate

3. Yellow precipitate

4. No precipitate

Which of the following is the correct order of second ionization energy?

1. V > Cr > Mn

2. V < Cr < Mn

3. V < Cr > Mn

4. V > Cr < Mn

The inner transition element is not represented by the atomic
number among 59, 74, 95, 102, and 104.

1. 59

2. 95

3. 102

4. 104

A substance is found to have a magnetic moment of 3.9 B.M. The ion may be 

1. Fe⁺³

2. Mn⁺²

3. Co⁺²

4. Cu⁺²