The complex that can exhibit optical activity among the following is:
1. [CoCl6]3-
2. [Co(en)CI4]-
3. cis-[Co(en)2Cl2]+
4. trans-[Co(en)2Cl2]+
2.335 g of compound X (empirical formal CoH12N4Cl3) upon treatment with excess AgNO3 solution produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X, respectively are:
[Given Atomic mass: Co = 59, Cl = 35.5, Ag = 108]
1. | 3, 6 | 2. | 3, 4 |
3. | 2, 4 | 4. | 4, 3 |
The geometry and magnetic property of , respectively, are
1. Tetrahedral, Paramagnetic
2. Tetrahedral, Diamagnetic
3. Square planar, Paramagnetic
4. Square planar, Diamagnetic
Among
(i) [Cr(en)3]3+
(ii) trans-[Cr(en)2Cl2]+
(iii) cis-[Cr(en)2Cl2]+
(iv) [Co(NH3)4Cl2]+
the optically active complexes are-
1. (i), (ii) and (iii)
2. (i) and (iii)
3. (ii) and (iii)
4. (ii) and (iv)
Among the following complexes, the one that can exist
as facial(fac) and meridional(mer) isomer is:
1. | [Co(NO2)3(NH3)3] | 2. | K3[FeCN6] |
3. | [Co(H2O)2(NH3)4]CI3 | 4. | [CoCl(NH3)5]CI |
The total number of geometrical isomers possible for an octahedral complex of are:
(M = transition metal; A, B and C are monodentate ligands)
1. | 3 | 2. | 4 |
3. | 5 | 4. | 6 |
The IUPAC name of [Co(ONO)(NH3)5]Cl2 is:
1. Pentamminenitrocobalt(II)chloride
2. Pentamminenitrsoocobalt(III)chloride
3. Pentaaminenitrito-O-cobalt(III)chloride.
4. Pentammineoxo-nitrocobalt(III)chloride
The metal carbonyl which is paramagnetic is:
1. | Ni | 2. | V |
3. | Cr | 4. | Fe |
1. NO3- acts as a monodentate ligand.
2. The Ce atom has a coordination number of 12.
3. The shape of the complex ion is an icosahedron.
4. The solution is used as an oxidizing agent.