The spin-only magnetic moments of ${\left[\mathrm{Mn}{\left(\mathrm{CN}\right)}_6\right]}^{4-} \mathrm{and} {\left[{\mathrm{MnBr}}_4\right]}^{2-}$ in Bohr Magnetons, respectively, are

1.  5.92 and 5.92

2.  4.89 and 1.73

3.  1.73 and 5.92

4.  1.73 and 1.73

The crystal field stabilization energies (CFSE) of high-spin and low-spin (d⁶) octahedral metal complexes in terms of Δ₀, respectively, are:

1.  -0.4 and -2.4

2.  -2.4 and -0.4

3.  -0.4 and 0.0

4.  -2.4 and 0.0

The oxidation state of cobalt in the following molecule is:

1. 3

2. 1

3. 2

4. 0

For a tetrahedral complex ${\left[{\mathrm{MCI}}_4\right]}^{2-}$, the spin-only magnetic moment is 3.83 B.M. The element M is 

1.  Co

2.  Cu

3.  Mn

4.  Fe

Tetrahedral and diamagnetic compound among the following is:

The number of ions produced in water by the dissolution of the complex having the empirical formula [Co(NH₃)₄Cl₂]CI is: 

1. 1

2. 2

3. 4

4. 3

Spin-only magnetic moments of [Fe(NH₃)₆]³⁺ and [FeF₆]^3-  in BM are, respectively :

In an aqueous solution, ${\left[\mathrm{Co}{\left({\mathrm{H}}_2\mathrm{O}\right)}_6\right]}^{2+}$ (X) reacts with molecular oxygen in the presence of excess liquor $N{H}_3$ to give a new complex Y. The number of unpaired electrons in X and Y are, respectively

1. 3, 1

2. 3, 0

3. 3, 3

4. 7, 0 

The energies of ${\mathrm{d}}_{\mathrm{xy}} \mathrm{and} {{\mathrm{d}}_{\mathrm{z}}}^2$ orbitals in octahedral and tetrahedral transition metal complexes are such that

1. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) > \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in both tetrahedral and octahedral complexes

2. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) < \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in both tetrahedral and octahedral complexes

3. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) > \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in tetrahedral but $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) < \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in octahedral complexes

4. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) < \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$  in tetrahedral but $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) > \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in octahedral complexes   

The number of geometrical isomers of [CrCl₂en(NH₃)₂] are:
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