Boiling of dil. HCl acid does not increase its concentration beyond 22.2 per cent because hydrochloric acid:

(1) is very volatile

(2) is extremely soluble in water

(3) forms a constant boiling mixture

(4) forms a saturated solution at this concentration

A 500 g toothpaste sample has 0.4 g fluoride concentration. The fluoride concentration in terms of ppm will be -

The correct statement regarding a solution of two components A and B exhibiting positive deviation from ideal behavior is :

If the relative decrease in vapour pressure is 0.4 for a solution containing 1 mol NaCl in 3 mol of ${\mathrm{H}}_2\mathrm{O}$, then percentage ionisation of NaCl will be -

1. 60%

2. 80%

3. 40%

4. 100%

The Henry's law constant for the solubility of N₂ gas in water at 298 K is 1.0 × 10⁵ atm. The mole fraction of N₂ in air is 0.8. The number of moles of N₂ formed from air dissolved in 10 moles of water at 298 K and 5 atm pressure is-

${\mathrm{C}}_6{\mathrm{H}}_6$ freezes at 5.5$°$C. At what temperature will a solution of 10.44 g of ${\mathrm{C}}_4{\mathrm{H}}_{10}$ in 200 g of ${\mathrm{C}}_6{\mathrm{H}}_6$ freeze ? K_f (${\mathrm{C}}_6{\mathrm{H}}_6$) = 5.12$°$C/m

1. 4.60$°$C

2. 0.89$°$C

3. 5.50$°$C

4. None of the above

The mixture among the following that forms maximum boiling azeotrope is:

1. Heptane + Octane
2. Water + Nitric acid
3. Ethanol + Water
4. Acetone + Carbon disulfide

During osmosis, the flow of water through a semi-permeable membrane is:

A solution containing 10 g/dm³ of urea (molecular mass = 60 g mol^-1) is isotonic with a 5 % solution of a non-volatile solute. The molecular mass of this non-volatile solute is:

The freezing point depression constant for water is 1.86 ^oC m^-1. If 5.00 g Na₂SO₄ is dissolved in 45.0 g H₂O, the freezing point is changed by -3.82 ^oC. The van’t Hoff factor for Na₂SO₄ is: