What is the enthalpy of formation of FeS (in kJ/mol) if 2.1 g of Fe combines with sulfur and releases 3.77 kJ of heat?
| 1. | – 3.77 | 2. | – 1.79 |
| 3. | – 100.5 | 4. | None of these |
Which is an extensive property?
| 1. | Temperature | 2. | Chemical potential |
| 3. | Gibbs free energy | 4. | Molar volume |
What is the amount of work done by an ideal gas, if the gas expands isothermally from \(10^{-3}~m^3\) to \(10^{-2}~m^3\) at \(300~K\)against a constant pressure of \(10^{5}~Nm^{-2}\)?
| 1. | \(+270 ~kJ\) | 2. | \(–900 ~J\) |
| 3. | \(+900 ~kJ\) | 4. | \(–900~ kJ\) |
Reversible expansion of an ideal gas under isothermal and adiabatic conditions are shown in the figure:
ABIsothermal expansion
ACAdiabatic expansion
Which of the following options is not correct?
| 1. | \(\Delta S_{\text {isothermal }}>\Delta S_{\text {adiabatic }} \) | 2. | \(T_A=T_B \) |
| 3. | \(W_{\text {isothermal }}>W_{\text {adiabatic }} \) | 4. | \(T_C>T_A\) |
Which of the following processes shows a decrease in entropy?
1. \(2 \text H \left(g\right)\rightarrow\text H_{2} \left(g\right)\)
2. Evaporation of water
3. Expansion of a gas at a constant temperature
4. Sublimation of a solid to a gas
Under the isothermal condition, a gas at \(300 \mathrm{~K}\) expands from \(0.1 \mathrm{~L}\) to \(0.25 \mathrm{~L}\) against a constant external pressure of 2 bar. The work done by the gas is:
| 1. | \(30 ~\mathrm {J} \) | 2. | \(-30 ~\mathrm{J} \) |
| 3. | \(5~ \mathrm{kJ}\) | 4. | \(25~ \mathrm{J}\) |
Assuming each reaction is carried out in an open container,
Reaction that shows ΔH=ΔE is :
1.
2.
3.
4.
The bond energy of H—H and Cl-Cl is 430 kJ
mol-1 and 240 kJ mol-1 respectively and ΔHf for HCl is -90 kJ mol-1. The bond enthalpy of HCl is:
1. 290
2. 380
3. 425
4. 245
A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.0ºC. As it does so, it absorbs 208 J of heat. The values of q and w for the process will be-
(R = 8.314 J/mol K) (ln 7.5 = 2.01)
| 1. | q = +208 J, w = -208 J | 2. | q = -208 J, w = -208 J |
| 3. | q = -208 J, w = + 208 J | 4. | q = +208 J, w = + 208 J |
1. 93 kJ mol-1
2. - 245 kJ mol-1
3. -93 kJ mol-1
4. 245 kJ mol-1