NCERT Section

3.4 NOMENCLATURE OF ELEMENTS WITH ATOMIC NUMBERS > 100

 The naming of the new elements had been traditionally the privilege of the discoverer (or discoverers) and the suggested name was ratified by the IUPAC. In recent years this has led to some controversy. The new elements with very high atomic numbers are so unstable that only minute quantities, sometimes only a few atoms of them are obtained. Their synthesis and characterisation, therefore, require highly sophisticated costly equipment and laboratory. Such work is carried out with competitive spirit only in some laboratories in the world. Scientists, before collecting the reliable data on the new element, at times get tempted to claim for its discovery. For example, both American and Soviet scientists claimed credit for discovering element 104. The Americans named it Rutherfordium whereas Soviets named it Kurchatovium. To avoid such problems, the IUPAC has made recommendation that until a new element’s discovery is proved, and its name is officially recognised, a systematic nomenclature be derived directly from the atomic number of the element using the numerical roots for 0 and numbers 1-9. These are shown in Table 3.4. The roots are put together in order of digits which make up the atomic number and “ium” is added at the end. The IUPAC names for elements with Z above 100 are shown in Table 3.5.

 


* Glenn T. Seaborg’s work in the middle of the 20th century starting with the discovery of plutonium in 1940, followed by those of all the transuranium elements from 94 to 102 led to reconfiguration of the periodic table placing the actinoids below the lanthanoids. In 1951, Seaborg was awarded the Nobel Prize in chemistry for his work. Element 106 has been named Seaborgium (Sg) in his honour.


Table 3.4 Notation for IUPAC Nomenclature of Elements
Screenshot from 2019-06-03 18-02-45
 Table 3.5 Nomenclature of Elements with Atomic Number Above 100

Screenshot from 2019-06-03 18-04-39

 

Thus, the new element first gets a temporary name, with symbol consisting of three letters. Later permanent name and symbol are given by a vote of IUPAC representatives from each country. The permanent name might reflect the country (or state of the country) in which the element was discovered, or pay tribute to a notable scientist. As of now, elements with atomic numbers up to 118 have been discovered. Official names of all elements have been announced by IUPAC.

 

Problem 3.1

What would be the IUPAC name and symbol for the element with atomic number 120? 

Solution

From Table 3.4, the roots for 1, 2 and 0 are un, bi and nil, respectively. Hence, the symbol and the name respectively are Ubn and unbinilium.