Ncert Exercises & Solutions

Match the following reactants in Column I with the corresponding reaction products in Column II.

Column I	Column II
A. $Benzene + {Cl}_{2} \overset{{AlCl}_{3}}{\to}$	1. Benzoic acid
B. $Benzene + {CH}_{3} Cl \overset{{AlCl}_{3}}{\to}$	2. Methyl phenyl ketone
C. $Benzene + {CH}_{3} COCl \overset{{AlCl}_{3}}{\to}$	3. Toluene
D. $Toluene \overset{{KMnO}_{4} / NaOH}{\to}$	4. Chlorobenzene
	5. Benzene hexachloride

Options:	A	B	C	D
1.	4	3	2	1
2.	1	2	3	5
3.	5	4	3	2
4.	4	5	3	2

Hint: Electrophilic aromatic substitution reaction

The reaction is as follows:

Column I	Column II
A. $Benzene + {Cl}_{2} \overset{{AlCl}_{3}}{\to}$	Friedel Craft's reaction
B. $Benzene + {CH}_{3} Cl \overset{{AlCl}_{3}}{\to}$	Friedel Craft's alkylation reaction Toluene
C. $Benzene + {CH}_{3} COCl \overset{{AlCl}_{3}}{\to}$	Methyl phenyl ketone (Friedel Craft's acetylation reaction)
D. $Toluene \overset{{KMnO}_{4} / NaOH}{\to}$	Oxidation reaction Benzoic acid