11.24 Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis:

(i) 1-Propoxypropane 

(ii) Ethoxybenzene

(iii) 2-Methoxy-2-methylpropane 

(iv) 1-Methoxyethane


 CH3CH2CHONa + CH3CH2CH2BrC2H5CH2-O-CH2C2H5+ NaBr
Sodium propoxide   1-Bromopropane                      1-Propoxypropane

(ii) 

(iii)            CH3                                          CH3
           |                                              |     
CH3CONa   +CH3BrCH3COCH3  + NaBr
           |                                               |
         CH3                                            CH3
Sodium 2- methyl  Bromomethane     2- methoxy -2- methlpropane
-2- propoxide

(iv)  CH3CH2ONa+ CH3CH3-Br CH3CH2-O-CH3+ NaBr
Sodium ethoxide  Bromomethane            1-Methoxyethane