Ncert Exercises & Solutions

Which of the following compounds would undergo S $_{N}$ 1 reaction faster and why?

Compound (B) will give S

_{N}

1 reaction faster than compound (A) because S

_{N}

1 reaction

will only depend upon the stability of carbocation. Benzyl chloride on onisation gives $C_{6} H_{5} \overset{+}{C} H_{2}$ carbocation which is resonance srabilised while the carbocation obtained from compound

(A)is not stabilised by resonance.

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