The unit that relates concentration of solution with its vapour pressure is: 

1. Mole fraction. 2. Parts per million.
3. Mass percentage. 4. Molality.

HINT: Henry's law
Explanation:
According to Henry's law partial pressure of gas in the solution is proportional to the mole fraction of gas in the solution.
p = KH x
where,                                                   KH =Henry’s constant
Hence, (1) mole fraction is the correct choice.