Oxidation of sulphur dioxide into sulphur trioxide in the absence of a catalyst is a slow process but this oxidation occurs easily in the atmosphere. Explain how does this happen? Give chemical reactions for the conversion of SO2 into SO3?

The oxidation of sulphur dioxide into sulphur trioxide can occur both photochemically or non-photochemically. In the near ultraviolet region, the SO2 molecules react with ozone photochemically.
SO2+O3hvSO3+O2
2SO2+O2hv2SO3
Non-photochemically, SO2 may be oxidised by molecular oxygen in presence of dust and soot particles.
2SO2+O2Particulates2SO3