Two liquids (A) and (B) can be separated by the method of fractional distillation. The boiling points of liquid (A) is less than boiling point of liquid (B). Which of the liquids do you expect to come out first in the distillate? Explain.


If the difference in boiling points of two liquids is not much, fractional distillation is used to separate them. In this technique, fractionating column is fitted over the mouth of the round bottom flask.
When vapours of a liquid mixture are passed through a fractionating column, the vapours of the low boiling of liquid (A) will move up while those of the high boiling liquid will condense and fall back into the flask. Therefore, liquid (A) with low boiling point will distill first.