Assertion (A): In the presentation 
\( \mathrm{E}_{\mathrm{Fe}^{3+}}^{\ominus} /_{ \mathrm{Fe}^{2+}}\) \( \text { and } \mathrm{E}_{\mathrm{Cu}^{2+}}^{\ominus} / _{\mathrm{Cu}^{\prime}} \mathrm{Fe}^{3+} / \mathrm{Fe}^{2+} \) and\(\text { } \mathrm{Cu}^{2+} / \mathrm{Cu}\) are redox couples.
Reason (R): A redox couple is the combination of the oxidised and reduced forms of a substance involved in an oxidation or reduction half cell.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Hint: A redox couple is the combination of the oxidised and reduced forms.
 

Explanation: A redox couple is defined as pair of compounds or elements having together the oxidised and reduced forms of it and taking part in an oxidation or reduction half-reaction. So, Fe3+/Fe2+ and Cu2+/Cu are redox couples.