4.12 H3PO3 can be represented by structures 1 and 2 shown below. Can these two structures be taken as the canonical forms of the resonance hybrid representing H3PO3 ? If not, give reasons for the same.

ncert solutions for class 11 chemistry chapter 4

 


According to experimental findings, all carbon to oxygen bonds in CO32- are equivalent.
Hence, it is inadequate to represent CO32- by a single Lewis structure having two single bonds and one double bond.
Therefore, carbonate ion is described as a resonance hybrid of the following structures:
class 11 chemistry ncert solutions chapter 4