Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However, oxygen has lower ionisation enthalpy than nitrogen. Explain.


Oxidation state of an element depends upon the electrons present in the outermost shell or eight minus the number of valence shell electrons (outermost shell electrons). e.g.,
Alkali metals (Group 1 elements) General valence shell electronic configuration -ns1; Oxidation state=+1
Alkaline earth metals (Group 2 elements) General valence shell electronic configuration -ns2; Oxidation state=+2.
Alkali metals and alkaline earth metals belong to s-block elements and elements of group 13 to group 18 are known as p-block elements.
Group 13 elements General valence shell electronic configuration -ns2np1; Oxidation states=+3 and +1.
Group 14 elements General valence shell electronic configuration -ns2np2; Oxidation states=+4 and +2.
Group 15 elements General valence shell electronic configuration -ns2np3; Oxidation states=-3, +3 and +5. Nitrogen shows +1, +2, +4 oxidation states also.
Group 16 elements General valence shell electronic configuration -ns2np4; Oxidation states=-2, +2, +4 and +6.
Group 17 elements General valence shell electronic configuration -ns2np5; Oxidation states=-1, Cl, Br and I also shows +1, +3, +5 and +7 oxidation states.
Group 18 elements General valence shell configuration -ns2np6. Oxidation state=zero.
Transition elements or d-block elements General electronic configuration -(n-1)d1-10ns1-2. These elements show variable oxidation states due to involvement of not only ns electrons but d or f-electrons (inner-transition elements) as well. Their most common oxidation states are +2 and +3.