Oxidation of nitrogen among the following reactions is indicated by -
1. \(\mathrm{N}_2 \rightarrow 2 \mathrm{NH}_3
\)
2. \(\mathrm{N}_2 \mathrm{O}_4 \rightarrow 2 \mathrm{NO}_2
\)
3. \(\mathrm{NO}_3{ }^{-} \rightarrow \mathrm{N}_2 \mathrm{O}_5
\)
4. \(\mathrm{NO}_2^{-} \rightarrow \mathrm{NO}_3^{-}\)