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A solution contains Na2CO3 and NaHCO3. 10 mL of the solution required 2.5 mL of 0.1 M H2SO4 for neutralisation using phenolphthalein as indicator. Methyl orange is then added when a further 2.5 mL of 0.2 M H2SO4 was required. The amount of Na2CO3 and NaHCO3 in 1 litre of the solution is:

1. 5.3g and 4.2g

2. 3.3g and 6.2g

3. 4.2g and 5.3g

4. 6.2g and 3.3g

Subtopic:  Millimole/Equivalent Concept |
Level 3: 35%-60%
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25 ml of a solution containing HCl and H2SO4 required 10 ml of a 1 N NaOH solution for neutralization. 20 ml of the same acid mixture on being treated with an excess of AgNO3 gives 0.1435 g of AgCl. The normality of HCl and normality of the H2SO4 are respectively

1. 0.40 N and 0.05 N

2. 0.05 N and 0.35 N

3. 0.05 N and 0.25 N

4. 0.40 N and 0.5 N 

Subtopic:  Millimole/Equivalent Concept |
Level 3: 35%-60%
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The oxide of metal contains 40% by mass of oxygen. The percentage of chlorine in the chloride of the metal is

1. 84.7

2. 74.7

3. 64.7

4. 44.7

Subtopic:  Millimole/Equivalent Concept |
 56%
Level 3: 35%-60%
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What volume of O2g measured at 1 atm and 273 K will be formed by the action of 100 mL of 0.5 N KMnO4 on hydrogen peroxide in an acid solution?

The skeleton equation for the reaction is

KMnO4+H2SO4+H2O2K2SO4+MnSO4+O2+H2O

1.  0.12 litre

2.  0.028 litre

3.  0.56 litre

4.  1.12 litre

Subtopic:  Millimole/Equivalent Concept |
 52%
Level 3: 35%-60%
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A solution of Na2S2O3 is standardized iodometrically against 0.167 g of KBrO3. This process requires 50 mL of the Na2S2O3 solution. What is the normality of the  Na2S2O3?

1. 0.2 N

2. 0.12 N

3. 0.72 N

4. 0.02 N

Subtopic:  Millimole/Equivalent Concept |
 55%
Level 3: 35%-60%
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The NH3 evolved due to complete conversion of N from 1.12 g sample of protein was absorbed in 45 mL of 0.4 N HNO3. The excess acid required 20 mL of 0.1 N NaOH. The % N in the sample is:

1.  8

2.  16

3.  20

4.  25

Subtopic:  Millimole/Equivalent Concept |
 51%
Level 3: 35%-60%
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100 mL of 10% NaOH (w/V) is added to 100 mL of 10% HCl (w/V). The resultant solution becomes:

1. Alkaline

2. Strongly alkaline

3. Acidic

4. Neutral

Subtopic:  Millimole/Equivalent Concept |
Level 3: 35%-60%
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Copper forms two oxides. For the same amount of copper, twice as much oxygen was used to form first oxide than to form second one. What is the ratio of the valencies of copper in first and second oxides?

1. 2:5

2. 1:6

3. 2:1

4. 1:2

Subtopic:  Millimole/Equivalent Concept |
 64%
Level 2: 60%+
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Read the following statements (S) and Explanation (E). Choose the correct answers from the codes (1), (2), (3) and (4):

S : An element may have variable equivalent mass.

E : Such elements should possess variable valency. 

1.  S is correct but E is wrong
2.  S is wrong but E is correct
3.  Both S and E are correct and E is correct explanation of S
4.  Both S and E are correct but E is not correct explanation of S

Subtopic:  Millimole/Equivalent Concept |
 70%
Level 2: 60%+
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If 1 gram of sodium hydroxide was treated with 25 mL of 0.75 M HCl solution, the mass of sodium hydroxide left unreacted is equal to:
1. 250 mg
2. Zero mg
3. 200 mg
4. 750 mg
Subtopic:  Millimole/Equivalent Concept |
 55%
Level 3: 35%-60%
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