At 1990 K and 1 atm pressure, there are an equal number of Cl2 molecules and Cl atoms in the reaction mixture.
The value of KP for the reaction Cl2( g)2Cl(g) under the above conditions is x × 10–1. The value of x is:

1. 4

2. 8

3. 5

4. 10

Subtopic:  Introduction To Equilibrium |
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For the reaction A(g)(B)(g), the value of the equilibrium constant at 300 K and 1 atm is equal to 100.0. The value of rG for the reaction at 300 K and 1 atm in J mol–1 is – xR, where x is:
(R = 8.31 J mol–1 K–1 and ln 10 = 2.3)

1. 1400

2. 1380

3. 1360

4. 1340

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For a reaction; X + Y  2Z, 1.0 mol of X, 1.5 mol of Y and 0.5 mol of Z were taken in a 1 L vessel and allowed to react. At equilibrium, the concentration of Z was 1.0 mol L–1 . The equilibrium constant of the reaction is x15. The value of x is:

1. 24

2. 13

3. 16

4. 19

Subtopic:  Introduction To Equilibrium |
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Given that the equilibrium constant   KC at 800 K for the reaction N2(𝑔)+3H2(𝑔)⇋2NH3(𝑔) is 64. What is the equilibrium constant Kat 800 K for the given-below  reaction is:
NH3(g) ⇌ 1/2N2(g) + 3/2H2(g)

1.  \(\dfrac{1}{4}\) 2. \(\dfrac{1}{8}\)
3. 8 4. \(\dfrac{1}{64}\)
Subtopic:  Introduction To Equilibrium |
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For the following reactions, equilibrium constants are given below:

S(s) + O2(g) SO2(g); K1 = 1052

2S(s) + 3O2(g) 2SO3(g); K2 = 10129

The equilibrium constant for the reaction, 2SO2(g) + O2(g) 2SO3(g) is:

1. 10154 2. 10181
3. 1025 4. 1077
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The equilibrium constant at 298 K for a reaction A + B  C + D is 100.
If the initial concentration of all the four species were 1 M each,
then equilibrium concentration of D (in mol L–1) will be :

1. 0.182 2. 0.818
3. 1.818 4. 1.182
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A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the COis converted into CO on the addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is :

1. 1.8 atm

2. 3 atm

3. 0.3 atm

4. 0.18 atm

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In a closed reaction vessel, Phosphorus pentachloride dissociates as follows:

\(\mathrm{PCl}_{5}(g) \rightleftharpoons \mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g)\)

If the total pressure at equilibrium of the reaction mixture is P and the degree of dissociation of PCl5  is x, the partial pressure of PCl3 will be:

1. \(\left(\frac{x}{x+1}\right) P\)

2. \(\left(\frac{2x}{x-1}\right) P\)

3. \(\left(\frac{x}{x-1}\right) P\)

4.  \(\left(\frac{x}{1-x}\right) P\)

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Consider the reaction equilibrium :  \(2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g) ; \quad \Delta H^{\circ}=-198 \mathrm{~kJ} \)

On the basis of Le-Chatelier's principle, the condition favorable for the forward reaction is : 

1. lowering of temperature as well as pressure 

2. increasing temperature as well as pressure 

3. lowering the temperature and increasing the pressure 

4. Any value of temperature and pressure 

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For the reaction equilibrium,  \(\mathrm{N}_{2} \mathrm{O}_{4}(g) \rightleftharpoons 2 \mathrm{NO}_2(g) \), the concentrations of N2O4  and NO2 at equilibrium are 4.8 \(\times\) 10-2  and 1.2 \(\times\) 10-2 mol L-1 respectively. The value of Kc for the reaction is:

1. 3.3 \(\times\) 10mol L-1 
2. 3 \(\times\) 10-1  mol L-1 
3. 3 \(\times\) 10-3  mol L-1 
4. 3 \(\times\) 10mol L-1  

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