A compound possessing optical isomerism provided it has the molecular formula C7H16, would be:

1. 2,3-Dimethyl pentane 2. 2,2-Dimethyl butane
3. 2-Methyl hexane 4. None of the above

Subtopic:  Alkanes, Alkenes and Alkynes - Conformations and Hybridisation |
 72%
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AIPMT - 2001
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 An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one.
The IUPAC name of ‘A’ is :

1. 3-Ethylpent-2-ene

2. 3-Ethylpent-2- yne

3. 2-Ethylpent-3-ene

4. 3-Ethylpent-4-yne

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 81%
From NCERT
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Arrange the following carbanions in order of their decreasing stability:

A. \(\mathrm{H}_3 \mathrm{C}-\mathrm{C} \equiv \mathrm{C}^{-}\)
B. \(\mathrm{H}-\mathrm{C} \equiv \mathrm{C}^{-}\)
C. \(\mathrm{H}_3 \mathrm{C}-\mathrm{\bar{C}H_2}\)

1. A>B>C

2. B>A>C

3. C>B>A

4. C>A>B

Subtopic:  Alkanes, Alkenes and Alkynes - Conformations and Hybridisation |
 71%
From NCERT
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The correct order of decreasing reactivity of the following compounds:

Chlorobenzene, 2,4-Dinitrochlorobenzene, and p-Nitrochlorobenzene

with an electrophile (E+)  is :

1. Chlorobenzene > p–Nitrochlorobenzene > 2,4-Dinitrochlorobenzene
2. p – Nitro chlorobenzene > 2, 4-Dinitrochlorobenzene > Chlorobenzene 
3. Chlorobenzene  > 2, 4-Dinitrochlorobenzene > p-Nitrochlorobenzene
4. 2, 4-Dinitrochlorobenzene > Chlorobenzene > p-Nitrochlorobenzene 

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 68%
From NCERT
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Ethyne ? Benzene 

The reagent used in the above conversion is:

1. Cr2O3

2. Alc. KOH

3. Red hot Fe

4. NaNH2/liq.NH3

Subtopic:  Aromatic Hydrocarbons - Reactions & Mechanism |
 88%
From NCERT
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Decreasing order of acidic behavior of benzene, n-hexane, and ethyne is -

1. Hexane > Ethyne > Benzene

2. Benzene > Hexane > Ethyne

3. Ethyne > Benzene > Hexane

4. Benzene > Ethyne > Hexene

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 84%
From NCERT
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The products formed after ozonolysis of Pent-2-ene are:

1. Ethanal and Methanal

2. Ethanal and Propanal

3. Ethanal and Butanal

4. Ethanal and  Ethanal

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 89%
From NCERT
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Benzene+CH3ClAlCl3 C6H5CH3

The mechanism & intermediate involved in the above reaction are:

1. Aromatic electrophilic substitution & carbocation

2. Aromatic Nucleophilic substitution & carbanion

3. Aromatic free radical substitution & Free radical

4. Carbene based substitution reaction & Carbene

Subtopic:  Aromatic Hydrocarbons - Benzene - Structure, Preparation & Chemical Reactions |
 84%
From NCERT
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The product(s) obtained via oxymercuration (HgSO4 + H2SO4 ) of but-1-yne is -

1. CH3CH2-C||O-CH3

2. CH3CH2 CH2-CHO

3. CH3CH2CHO + HCHO

4. CH3 CH2COOH + HCOOH

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 69%
From NCERT
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Which of the following Hydrocarbon has the highest octane number?

1. Methane

2. Ethane

3. Iso-octane

4. Triptane

Subtopic:  Aliphatic Hydrocarbon- Physical Properties |
 76%
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