1. | \(\dfrac{-\Delta[\mathrm{H}I]}{\Delta t}=\dfrac{2 \Delta\left[\mathrm{H}_2\right]}{\Delta t}\) | 2. | \(\dfrac{-\Delta[\mathrm{HI}]}{\Delta t}=\dfrac{4\Delta\left[\mathrm{I}_2\right]}{\Delta t}\) |
3. | \(\dfrac{-\Delta[\mathrm{HI}]}{\Delta t}=\dfrac{4 \Delta\left[\mathrm{H}_2\right]}{\Delta t}\) | 4. | \( \dfrac{-\Delta[\mathrm{HI}]}{\Delta t}=\dfrac{\Delta\left[\mathrm{H}_2\right]}{\Delta t}\) |
1. | \(-\Delta [A] \over \Delta t\) | 2. | \(-3\Delta [A] \over 2\Delta t\) |
3. | \(-2\Delta [A] \over 3\Delta t\) | 4. | \(\Delta [A] \over \Delta t\) |
For the reaction, 2A → B, rates= k[A]2. If the concentration of reactant is doubled, then the:
(a) | rate of reaction will be doubled. |
(b) | rate constant will remain unchanged, however rate of reaction is directly proportional to the rate constant. |
(c) | rate constant will change since the rate of reaction and rate constant are directly proportional to each other. |
(d) | rate of reaction will increase by four times. |
Identify the set of correct statements & choose the correct answer from the options given below:
1. | (a) and (c) only | 2. | (a) and (b) only |
3. | (b) and (d) only | 4. | (c) and (d) only |
1. | 1 × 10–2 mol L–1 s–1 and 30 × 10–2 mol L–1 |
2. | 10 × 10–2 mol L–1 s–1 and 10 × 10–2 mol L–1 |
3. | 1 × 10–2 mol L–1 s–1 and 10 × 10–2 mol L–1 |
4. | 10 × 10–2 mol L–1 s–1 and 30 × 10–2 mol L–1 |
For the chemical reaction the correct option is:
1. | 2. | ||
3. | 4. |
The correct statement among the following is:
1. | the rate of a first-order reaction does not depend on reactant concentration; the rate of a second-order reaction does depend on reactant concentrations. |
2. | the half-life of a first-order reaction does not depend on [A]o; the half-life of a second-order reaction does depend on [A]0 |
3. | a first-order reaction can be catalyzed; a second-order reaction cannot be catalyzed. |
4. | the rate of a first-order reaction does depend on reactant concentrations; the rate of a second-order reaction does not depend on reactant concentrations |
1. | Internal energy | 2. | Enthalpy |
3. | Activation energy | 4. | Entropy |
In a reaction, A + B → Product, the rate is doubled when the concentration of B is doubled, and the rate increases by a factor of 8, when the concentrations of both the reactants (A and B) are doubled. The rate law for the reaction can be written as:
1. Rate = k[A][B]2
2. Rate = k[A]2[B]2
3. Rate = k[A][B]
4. Rate = k[A]2[B]
Which of the following statements about the order of reaction is incorrect?
1. | Order is not influenced by the stoichiometric coefficient of the reactants. |
2. | Order of reaction is the sum of power to the concentration terms of reactants to express the rate of reaction. |
3. | The order of reaction is always a whole number. |
4. | Order can be determined by experiments only. |
The unit of rate constant for a zero-order reaction is:
1.
2.
3.
4.