| 1. | N-ethylethanamine > ethanamine > N -methylaniline > benzenamine | 
| 2. | benzenamine > ethanamine > N -methylaniline >N-ethylethanamine | 
| 3. | N -methylaniline > benzenamine > ethanamine >N-ethylethanamine | 
| 4. | N-ethylethanamine > ethanamine > benzenamine >N-methylaniline | 
| Statement I: | Benzenediazonium salt is prepared by the reaction of aniline with nitrous acid at \(273-278~ \text{K}.\) It decomposes easily in the dry state | 
| Statement II: | Insertion of iodine into the benzene ring is difficult and hence iodobenzene is prepared through the reaction of benzenediazonium salt with \(KI.\) | 
| 1. | Statement I is correct; Statement II is incorrect | 
| 2. | Statement I is incorrect; Statement II is correct | 
| 3. | Both Statement I and Statement II are correct | 
| 4. | Both Statement I and Statement II are incorrect | 
| Statement I: | Aniline does not undergo Friedel-Crafts alkylation reaction. | 
| Statement II: | Aniline cannot be prepared through Gabriel synthesis. | 
| 1. | Both Statement I and Statement II are incorrect. | 
| 2. | Statement I is correct and Statement II is incorrect. | 
| 3. | Statement I is incorrect and Statement II is correct. | 
| 4. | Both Statement I and Statement II are correct. | 

| List-I (Amine) | List-II \(\textbf{(pK}_{\beta} ~\textbf{value}) \) | ||
| A. | Benzenamine | I. | 3.38 | 
| B. | Phenylmethanamine | II. | 9.38 | 
| C. | Methenamine | III. | 4.70 | 
| D. | N-Ethylethanamine | IV. | 3.0 | 
| 1. | A-II, B-III, C-I, D-IV | 2. | A-III, B-II, C-I, D-IV | 
| 3. | A-II, B-I, C-III, D-IV | 4. | A-I, B-III, C-II, D-IV | 
| List-I (Reagent) | List-II (name of the reaction) | ||
| A. | Carbylamine test | I. | Phenol | 
| B. | Bayer's test | II. | Acetone | 
| C. | Iodoform test | III. | Ethylene | 
| D. | Phthalein dye test | IV. | Aniline | 
| Statement I: | Benzendiazonium chloride is a colourless crystalline solid. It is insoluble in water but reacts with water when warmed. | 
| Statement II: | Benzendiazonium chloride on reacting with HCI in presence of copper powder gives chlorobenzene as the product. This is an example of Gatterman reaction. | 
| 1. | Both Statement I and Statement II is true. | 
| 2. | Both Statement I and Statement II is false. | 
| 3. | Statement I is true but Statement II is false. | 
| 4. | Statement I is false but Statement II is true. | 
| 1. |   | 
| 2. |  | 
| 3. |  | 
| 4. |  | 
| 1. | 2. | ||
| 3. | 4. |