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When 19.5 g of fluoroacetic acid (CH2FCOOH) is dissolved in 500 g of water, the observed depression in the freezing point was found to be 1.00 K. The Van’t Hoff factor and the dissociation constant of the fluoroacetic acid, respectively are: (Given: \(K_f\) for water = 1.86 K kg mol⁻¹, Molar mass of CH2FCOOH = 78 g mol⁻¹)

1. 20.75 , 4.77 × 10–3 2. 1.075 ,  4.77 × 10–2
3. 2.073 , 3.07 × 10–4 4. 1.075 , 3.07 × 10–3
Subtopic:  Van’t Hoff Factor |
Level 3: 35%-60%
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