When 19.5 g of fluoroacetic acid (CH2FCOOH) is dissolved in 500 g of water, the observed depression in the freezing point was found to be 1.00 K. The Van’t Hoff factor and the dissociation constant of the fluoroacetic acid, respectively are: (Given: \(K_f\) for water = 1.86 K kg mol⁻¹, Molar mass of CH2FCOOH = 78 g mol⁻¹)
| 1. | 20.75 , 4.77 × 10–3 | 2. | 1.075 , 4.77 × 10–2 |
| 3. | 2.073 , 3.07 × 10–4 | 4. | 1.075 , 3.07 × 10–3 |