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Q. No.For an endothermic reaction:
A. \(q_p \) (heat at constant pressure) is negative.
B. \(\Delta _r H \) (enthalpy change of the reaction) is positive.
C. \(\Delta _r H \) is negative.
D. \(q_p \) is positive.
Which of the following combinations is correct?
A. \(q_p \) (heat at constant pressure) is negative.
B. \(\Delta _r H \) (enthalpy change of the reaction) is positive.
C. \(\Delta _r H \) is negative.
D. \(q_p \) is positive.
Which of the following combinations is correct?
| 1. | B and D | 2. | C and D |
| 3. | A and B | 4. | A and C |
Subtopic: Thermodynamics' Properties and process |
73%
Level 2: 60%+
NEET - 2024
Hints
Match List I with List II.
Choose the correct answer from the options given below:
| List-I (Process) | List-II (Conditions) | ||
| A. | Isothermal process | I. | No heat exchange |
| B. | Isochoric process | II. | Carried out at constant temperature |
| C. | Isobaric process | III. | Carried out at constant volume |
| D. | Adiabatic process | IV. | Carried out at constant pressure |
| 1. | \(\text { A-IV, B-II, C-III, D-I }\) | 2. | \(\text { A-I, B-II, C-III, D-IV }\) |
| 3. | \(\text { A-II, B-III, C-IV, D-I }\) | 4. | \(\text { A-IV, B-III, C-II, D-I }\) |
Subtopic: Thermodynamics' Properties and process |
86%
Level 1: 80%+
NEET - 2024
Hints
Match the processes or properties in List-I with their corresponding characteristics in List-II.
Choose the correct answer from the options given below:
| List-I (Process/Property) |
List-II (Characteristic) |
||
| A. | Adiabatic process | I. | Independent of the amount of substance |
| B. | Reversible process | II. | The reaction can proceed in both directions, from reactants to products and vice versa |
| C. | Intensive property | III. | No transfer of heat between the system and the surrounding |
| D. | Extensive property | IV. | Dependent on the amount of substance |
| 1. | A-II, B-III, C-IV, D-I | 2. | A-I, B-II, C-IV, D-III |
| 3. | A-III, B-II, C-I, D-IV | 4. | A-I, B-II, C-III, D-IV |
Subtopic: Classification of System, Extensive & Intensive Properties |
93%
Level 1: 80%+
NEET - 2024
Hints
Consider the following reaction:
\(\mathrm{A}_2(\mathrm{~g})+3 \mathrm{~B}_2(\mathrm{~g}) \rightarrow 2 \mathrm{AB}_3(\mathrm{~g})\)
If at 300K, the enthalpy change for the above reaction is +15 kJ, then the internal energy change is:
\(\mathrm{A}_2(\mathrm{~g})+3 \mathrm{~B}_2(\mathrm{~g}) \rightarrow 2 \mathrm{AB}_3(\mathrm{~g})\)
If at 300K, the enthalpy change for the above reaction is +15 kJ, then the internal energy change is:
| 1. | 19.98 K J | 2. | 200 J |
| 3. | 1999 J | 4. | 1.9988 kJ |
Subtopic: Enthalpy & Internal energy |
77%
Level 2: 60%+
NEET - 2024
Hints
For the reaction, 2Cl(g) Cl2(g), the correct option is:
| 1. | \(\Delta_{\mathrm{r}} \mathrm{H}>0\) and \(\Delta_{\mathrm{r}} \mathrm{S}<0 \) | 2. | \(\Delta_{\mathrm{r}} \mathrm{H}<0\) and \( \Delta_{\mathrm{r}} \mathrm{S}>0 \) |
| 3. | \(\Delta_{\mathrm{r}} \mathrm{H}<0 \) and \(\Delta_{\mathrm{r}} \mathrm{S}<0 \) | 4. | \(\Delta_{\mathrm{r}} \mathrm{H}>0\) and \( \Delta_{\mathrm{r}} \mathrm{S}>0\) |
Subtopic: Enthalpy & Internal energy | Spontaneity & Entropy |
61%
Level 2: 60%+
NEET - 2020
Hints
The standard enthalpy of vaporization for water at 100 oC is 40.66 kJ mol–1. The internal energy of vaporization of water at 100 oC (in kJ mol–1) is:
(Assume water vapour behaves like an ideal gas.)
| 1. | +37.56 | 2. | –43.76 |
| 3. | +43.76 | 4. | +40.66 |
Subtopic: Enthalpy & Internal energy |
61%
Level 2: 60%+
AIPMT - 2012
Hints
Work done during reversible isothermal expansion of one mole of hydrogen gas at 25°C from a pressure of 20 atmospheres to a pressure of 10 atmospheres is:
(Given: R = 2.0 cal K–1 mol–1)
(Given: R = 2.0 cal K–1 mol–1)
| 1. | –413.14 calories | 2. | 413.14 calories |
| 3. | 100 calories | 4. | 0 calorie |
Subtopic: First Law of Thermodynamics |
72%
Level 2: 60%+
NEET - 2024
Hints
Determine \(\Delta U\) for the process where, one mole of an ideal gas at 300 K is expanded isothermally from 1 L to 10 L volume:
(Use R = 8.314 J K–1 mol–1)
(Use R = 8.314 J K–1 mol–1)
| 1. | 1260 J | 2. | 2520 J |
| 3. | 5040 J | 4. | 0 J |
Subtopic: First Law of Thermodynamics |
80%
Level 1: 80%+
NEET - 2022
Hints
What is the amount of work done by an ideal gas, if the gas expands isothermally from \(10^{-3}~m^3\) to \(10^{-2}~m^3\) at \(300~K\)against a constant pressure of \(10^{5}~Nm^{-2}\)?
| 1. | \(+270 ~kJ\) | 2. | \(–900 ~J\) |
| 3. | \(+900 ~kJ\) | 4. | \(–900~ kJ\) |
Subtopic: First Law of Thermodynamics |
72%
Level 2: 60%+
NEET - 2019
Hints
A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5atm from an initial volume of 2.50 L to a final volume of 4.50L. The change in internal energy U of the gas in joules will be:
| 1. | –500J | 2. | –505J |
| 3. | –506J | 4. | –508J |
Subtopic: First Law of Thermodynamics |
Level 3: 35%-60%
NEET - 2017
Hints
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