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Q. No.Identify the incorrect statement.
| 1. | \(\mathrm{PEt}_3\) and \(\mathrm{Asph}_3\) as ligands can form \(\mathrm{d} \pi-\mathrm{d} \pi\) bond with transition metals. |
| 2. | The \(\mathrm{N}-\mathrm{N}\) single bond is as strong as the \(\mathrm{P}-\mathrm{P}\) single bond. |
| 3. | Nitrogen has unique ability to form \(\mathrm{p \pi-p \pi}\) multiple bonds with nitrogen, carbon and oxygen. |
| 4. | Nitrogen cannot form \(\mathrm{d} \pi-\mathrm{p} \pi\) bond as other heavier elements of its group. |
Subtopic: Group 15 - Preparation, Properties & Uses |
78%
Level 2: 60%+
NEET - 2024
Hints
Identify the incorrect statement about \(\mathrm{PCl_5}\).
| 1. | \(\mathrm{PCl_5}\) possesses two different \(\mathrm{Cl-P-Cl}\) bond angles. |
| 2. | All five \(\mathrm{P-Cl}\) bonds are identical in length. |
| 3. | \(\mathrm{PCl_5}\) exhibits sp3d hybridisation. |
| 4. | \(\mathrm{PCl_5}\) consists of five \(\mathrm{P-Cl}\) (sigma) bonds. |
Subtopic: Group 15 - Preparation, Properties & Uses |
79%
Level 2: 60%+
NEET - 2024
Hints
The reaction that is a part of large scale industrial preparation of nitric acid is:
| 1. | \(\mathrm{NaNO}_3+\mathrm{H}_2 \mathrm{SO}_4\xrightarrow[500~K, \ 9\text{ bar}]{Pt} \mathrm{NaHSO}_4+\mathrm{HNO}_3\) |
| 2. | \(4 \mathrm{NH}_3+5 \mathrm{O}_2 \text{(from air)}\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{NO}+6 \mathrm{H}_2 \mathrm{O}\) |
| 3. | \(4 \mathrm{HPO}_3+2 \mathrm{~N}_2 \mathrm{O}_5\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{P}_4 \mathrm{O}_{10}\) |
| 4. | \(\mathrm{Cu}\left(\mathrm{NO}_3\right)_2+2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O} \\ \xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{Cu}\) |
Subtopic: Group 15 - Preparation, Properties & Uses |
60%
Level 2: 60%+
NEET - 2022
Hints
The correct order for boiling points of the following compounds is:
| 1. | AsH3 > PH3 > NH3 > SbH3 > BiH3 |
| 2. | BiH3 > SbH3 > NH3 > AsH3 > PH3 |
| 3. | NH3 > PH3 > AsH3 > SbH3 > BiH3 |
| 4. | PH3 > NH3 > AsH3 > SbH3 > BiH3 |
Subtopic: Group 15 - Preparation, Properties & Uses |
65%
Level 2: 60%+
NEET - 2022
Hints
Among the following oxoacids of phosphorus, the strongest reducing property is for:
1. H4P2O7
2. H3PO3
3. H3PO2
4. H3PO4
1. H4P2O7
2. H3PO3
3. H3PO2
4. H3PO4
Subtopic: Group 15 - Preparation, Properties & Uses |
66%
Level 2: 60%+
NEET - 2019
Hints
The incorrect statement regarding oxoacids of phosphorus is:
| 1. | Orthophosphoric acid is used in the manufacture of triple superphosphate. |
| 2. | Hypophosphorous acid is a diprotic acid. |
| 3. | All oxoacids contain tetrahedral four coordinated phosphorus. |
| 4. | All oxoacids contain at least one P=O unit and one P-OH group. |
Subtopic: Group 15 - Preparation, Properties & Uses |
61%
Level 2: 60%+
AIPMT - 2012
Hints
Links
Given below are two statements:
In the light of the above statements, choose the most appropriate answer from the options given below:
1. Statement I is incorrect but Statement II is correct
2. Both Statement I and Statement II are correct
3. Both Statement I and Statement II are incorrect
4. Statement I is correct but Statement II is incorrect
| Statement I: | The boiling points of the following hydrides of group 16 elements increase in the order \(\mathrm{H}_{2} \mathrm{O}<\mathrm{H}_{2} \mathrm{~S}<\mathrm{H}_{2} \mathrm{Se}<\mathrm{H}_{2} \mathrm{Te} \) |
| Statement II: | The boiling points of these hydrides increase with the increase in molar mass. |
1. Statement I is incorrect but Statement II is correct
2. Both Statement I and Statement II are correct
3. Both Statement I and Statement II are incorrect
4. Statement I is correct but Statement II is incorrect
Subtopic: Group 16 - Preparation, Properties & Uses |
Level 3: 35%-60%
NEET - 2022
Hints
Subtopic: Group 16 - Preparation, Properties & Uses |
86%
Level 1: 80%+
NEET - 2019
Hints
Subtopic: Group 16 - Preparation, Properties & Uses |
Level 3: 35%-60%
NEET - 2017
Hints
Which of the following reactions does not exhibit the oxidising behaviour of H2SO4?
1. Cu + 2H2SO4 → CuSO4 + SO2 + 2H2O
2. 3S + 2H2SO4 → 3SO2 + 2H2O
3. C + 2H2SO4 → CO2 + 2SO2 + 2H2O
4. CaF2 + H2SO4 → CaSO4 + 2HF
Subtopic: Group 16 - Preparation, Properties & Uses |
79%
Level 2: 60%+
NEET - 2016
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