| 1. | N-ethylethanamine > ethanamine > N -methylaniline > benzenamine |
| 2. | benzenamine > ethanamine > N -methylaniline >N-ethylethanamine |
| 3. | N -methylaniline > benzenamine > ethanamine >N-ethylethanamine |
| 4. | N-ethylethanamine > ethanamine > benzenamine >N-methylaniline |
| Statement I: | Aniline does not undergo Friedel-Crafts alkylation reaction. |
| Statement II: | Aniline cannot be prepared through Gabriel synthesis. |
| 1. | Both Statement I and Statement II are incorrect. |
| 2. | Statement I is correct and Statement II is incorrect. |
| 3. | Statement I is incorrect and Statement II is correct. |
| 4. | Both Statement I and Statement II are correct. |
| 1. | 2. | ||
| 3. | 4. |
| 1. | |
| 2. | ![]() |
| 3. | ![]() |
| 4. | ![]() |
| Column-I (Reaction) |
Column-II (Product formed) |
||
| (a) | Gabriel synthesis | (i) | Benzaldehyde |
| (b) | Kolbe synthesis | (ii) | Ethers |
| (c) | Williamson synthesis | (iii) | Primary amines |
| (d) | Etard reaction | (iv) | Salicylic acid |
| (a) | (b) | (c) | (d) | |
| 1. | (iii) | (i) | (ii) | (iv) |
| 2. | (ii) | (iii) | (i) | (iv) |
| 3. | (iv) | (iii) | (i) | (ii) |
| 4. | (iii) | (iv) | (ii) | (i) |
Match list-I with list-II:
| List-I (Amines) | List-II (pKb values) | ||
| (a) | N-Methylmethanamine | (i) | 9.30 |
| (b) | Ammonia | (ii) | 9.38 |
| (c) | N-Methylaniline | (iii) | 4.75 |
| (d) | Benzenamine | (iv) | 3.27 |
| (a) | (b) | (c) | (d) | |
| 1. | (iv) | (ii) | (i) | (iii) |
| 2. | (iv) | (iii) | (i) | (ii) |
| 3. | (iii) | (iv) | (i) | (ii) |
| 4. | (i) | (iv) | (iii) | (ii) |
| 1. | Ethylamine | 2. | Methylamine |
| 3. | Propylamine | 4. | Aniline |
The correct statement regarding the basicity of arylamines is:
| 1. | Arylamines are generally more basic than alkylamines because the lone-pair electrons of nitrogen are not delocalized by interaction with the aromatic ring π-electron system. |
| 2. | Arylamines are generally more basic than alkylamines because of the aryl group +I effect. |
| 3. | Arylamines are generally more basic than alkylamines because the nitrogen atom in arylamines is sp-hybridized. |
| 4. | Arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalized by interaction with the aromatic ring π-electron system. |
The number of structural isomers possible from the molecular formula C3H9N is?
1. Four (4)
2. Five (5)
3. Two (2)
4. Three (3)
Mark the reaction that does not yield aniline from the given options:
| 1. | Hydrolysis of phenyl isocyanide with an acidic solution |
| 2. | Degradation of benzamide with bromine in alkaline solution |
| 3. | Reduction of nitrobenzene with H2/Pd in ethanol |
| 4. | Treatment of potassium salt of phthalimide with chlorobenzene followed by hydrolysis in an aqueous NaOH solution |