The name of the electrophile involved in the below reaction is:

1. Dichloromethyl cation \((^{+}CHCl_{2})\)

2. Formyl cation \((^{+}CHO)\)

3. Dichloromethyl anion \((^{-}CHCl_{2})\)

4. Dichlorocarbene (:CCl2)

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to:

1. Formation of intramolecular H-bonding
2. Formation of carboxylate ion
3. More extensive association of carboxylic acid via van der waals force of attraction
4. Formation of intermolecular H-bonding
Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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What is the correct order of the carboxylic acids' strength?

I. II. III.
 
1. I > II > III 2. II > III > I
3. III > II > I 4. II > I > III
Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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The correct statement regarding a carbonyl compound with a hydrogen atom on its alpha-carbon is:

1. A carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as aldehyde-ketone equilibration.
2. A carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as carbonylation.
3. A carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as keto-enol tautomerism.
4. A carbonyl compound with a hydrogen atom on its alpha-carbon never equilibrates with its corresponding enol.
Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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A reagent that can distinguish cis-cyclopenta-1,2-diol from the trans-isomer is:
1. Ozone
2. MnO2
3. Aluminium isopropoxide
4. Acetone
Subtopic:  Aldehydes & Ketones: Preparation & Properties |
From NCERT
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The product formed by the reaction of an aldehyde with a primary amine is:
1. Ketone
2. Carboxylic acid
3. Aromatic acid
4. Schiff base

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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The reaction of a carbonyl compound with one of the following reagents involves nucleophilic addition followed by the elimination of water. The reagents are:

1. A Grignard reagent.
2. Hydrazine in the presence of a feebly acidic solution.
3. Hydrocyanic acid.
4. Sodium hydrogen sulphite.

Subtopic:  Isomers & Reaction Mechanism |
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Treatment of cyclopentanone with methyl lithium generates:

1. Cyclopentanonyl cation

2. Cyclopentanonyl radical

3. Cyclopentanonyl biradical

4. Cyclopentanonyl anion

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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Compounds that can exhibit tautomerism, are:

1. l and ll
2. l and lll
3. ll and lll
4. l, ll and lll

Subtopic:  Isomers & Reaction Mechanism |
 53%
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An organic compound X having molecular formula C5H10O yields phenyl hydrazone and gives a negative response to the iodoform test and Tollen's test. It produces n-pentane on reduction. X could be:

1. Pentanal
2. 2-Pentanone
3. 3-Pentanone
4. n-Amyl alcohol
Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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