The order of energy absorbed which is responsible for the color of complexes is:
\((A) \ \left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}(\text { en })_{2}\right]^{2+}\)
\( (B) \ \left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}(\mathrm{en})\right]^{2+} and\)\( (C) \ \left[\mathrm{Ni}(\mathrm{en})_{3}\right]^{2+}\)
1. B > A > C  2. A > B > C 
3. C > B > A  4. C > A > B
Subtopic:  VBT, CFT & their Limitations |
 62%
From NCERT
NEET - 2022
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The correct order of spin-only magnetic moment for the given complexes is: 

1. \([Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} > [Fe(CN)_6]^{3-} \)
2. \([Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} \)
3. \([MnCl_6]^{3-} >[Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} \)
4. \([MnCl_6]^{3-} > [Co(H_2O_6]^{2+} > [Fe(CN)_6]^{3-} \)

Subtopic:  VBT, CFT & their Limitations |
 58%
From NCERT
NEET - 2022
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Match Column I with Column II, Columns I and II represent complexes and magnetic moment (BM) respectively. 

Column I Column II
(a). [FeCN6]3- (i). 5.92 BM
(b). [Fe(H2O)6]3+ (ii). 0 BM
(c). [Fe(CN)6]4- (iii). 4.90 BM
(d). [Fe(H2O)6]2+ (iv). 1.73 BM

Choose the correct answer from the options given below:

(a). (b). (c). (d).
1. (i). (iii). (iv). (ii).
2. (iv). (i). (ii). (iii).
3. (iv). (ii). (i). (iii).
4. (ii). (iv). (iii). (i).
Subtopic:  VBT, CFT & their Limitations |
 65%
From NCERT
NEET - 2021
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What is the correct electronic configuration of the central atom in K4FeCN6 based on crystal field theory:

1. e4 t2g  2

2. t2g  4 eg2

3. t2g  6 eg0

4. e3 t2g 3

Subtopic:  VBT, CFT & their Limitations |
 79%
From NCERT
NEET - 2019
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The crystal field stabilization energy (CFSE) for [CoCl6]4- is 18000 cm-1.
The CFSE for [CoCl4]2-  will be:

1. 6000 cm-1

2. 16000 cm-1

3. 18000 cm-1

4. 8000 cm-1

Subtopic:  VBT, CFT & their Limitations |
 69%
From NCERT
NEET - 2019
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The geometry and magnetic behaviour of the complex [Ni(CO)4] are:
 

1. Square planar geometry and Diamagnetic
2. Tetrahedral geometry and Diamagnetic
3. Square planar geometry and Paramagnetic
4. Tetrahedral geometry and Paramagnetic

Subtopic:  VBT, CFT & their Limitations |
 58%
From NCERT
NEET - 2018
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The correct increasing order for the wavelengths of absorption in complexes of Co3+ is:

1. [Co(H2O)6]3+ < [Co(en)3]3+ < [Co(NH3)6]3 +

2. [Co(H2O)6]3+ <  [Co(NH3)6]3+ <  [Co(en)3]3+

3. [Co(NH3)6]3+ < [Co(en)3]3+ < [Co(H2O)6]3+

4. [Co(en)3]3+ <  [Co(NH3)6]3+ < [Co(H2O)6]3+

Subtopic:  VBT, CFT & their Limitations |
 57%
From NCERT
NEET - 2017
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The correct statement among the following regarding [Mn(CN)6]3-is:

1. It is sp3d2 hybridized and tetrahedral.

2. It is d2sp3 hybridized and octahedral.

3. It is dsp2 hybridised and square planar.

4. It is sp3d2 hybridised and octahedral.

Subtopic:  VBT, CFT & their Limitations |
 79%
From NCERT
NEET - 2017
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The hybridization involved in the complex NiCN42-is:
(Atomic number of Ni=28)

1. dsp2

2. sp3

3. d2sp2

4. d2sp3

Subtopic:  VBT, CFT & their Limitations |
 81%
From NCERT
NEET - 2015
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An ion, among the following, that has a magnetic moment of 2.84 BM is:
(At. no. Ni = 28, Ti = 22, Cr = 24, Co = 27)

1. Ni2+
2. Ti3+
3. Cr2+
4. Co2+

Subtopic:  VBT, CFT & their Limitations |
 79%
From NCERT
NEET - 2015
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