KMnO4 acts as an oxidising agent in alkaline 
medium. When alkaline KMnO4 is treated 
with KI,  iodide ion is oxidised to ......... .

1.  I2
2.  IO-
3.  IO3-
4.  IO4-

Subtopic:  Chemistry of Mn and Cr Compounds |
 84%
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Which of the following statements is not correct?

1. Copper liberates hydrogen from acids

2. In its higher oxidation states, manganese forms stable compounds with oxygen and fluorine

3. Mn3+ and Co3+ are oxidising agents in an aqueous solution

4. Ti2+ and Cr2+ are reducing agents in an aqueous solution

Subtopic:  d-Block Elements- Properties & Uses |
 73%
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When acidified K2Cr2O7 the solution is added to Sn++ salt then Sn++ changes to

1. Sn
2. Sn3+
3. Sn4+
4. Sn+

Subtopic:  d-Block Elements- Properties & Uses |
 85%
From NCERT
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Highest oxidation state of manganese in fluoride is +4(MnF4) but highest oxidation state in oxides is +7(Mn2O7) because

1. Fluorine is more electronegative than oxygen
2. Fluorine does not possess d orbitals
3. Fluorine stabilises lower oxidation state
4. In covalent compounds, fluorine can form single bond only while oxygen forms double bond

Subtopic:  d-Block Elements- Properties & Uses |
 78%
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Although zirconium belongs to 4d transition series and hafnium to 5d transition series even then they show similar physical and chemical properties because............. .

1. Both belong to d-block

2. Both have same number of electrons

3. Both have similar atomic radius

4. Both belong to the same group of the Periodic Table

Subtopic:  d-Block Elements- Properties & Uses |
 84%
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Why is HCl not used to make the medium acidic in oxidation reactions of KMnO4 in acidic medium?

1. Both HCl and  KMnO4 act as oxidising agents
2. KMnO4 oxidises HCl into Cl2, which is also an oxidising agent
3. KMnO4  is a weaker oxidising agent than HCl
4. KMnO4 acts as a reducing agent in the presence of HCl

Subtopic:  Chemistry of Mn and Cr Compounds |
 83%
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Match Column I (Catalyst) with Column II (Process), and mark the appropriate option:

Column I - (Catalyst) Column II - (Process)
A. Ni in the presence of hydrogen 1. Contact process
B. Cu2Cl2 2. Vegetable oil to ghee
C. V2O5 3. Sandmeyer reaction
D. Finely divided iron 4. Haber's process
5.  Decomposition of  KClO3
 

Codes:

A B C D
1. 3 4 2 5
2. 2 3 1 4
3. 5 4 3 2
4. 4 5 3 2
Subtopic:  d-Block Elements- Properties & Uses |
 89%
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Match the compounds/elements given in Column I with uses given in Column II.

Column 
(Compound/element)
Column II
(Use)
A. Lanthanoid oxide 1. Petroleum cracking
B.  Lanthanoid 2.  Television screen
C. Mischmetal 3. Lanthanoid metal + iron
D. Mixed oxides of lanthanoids are
employed
4. Production of iron alloy

Codes
 

Options: A B C D
1. 2 1 4 3
2. 1 2 3 4
3. 2 4 3 1
4. 4 1 3 2
Subtopic:  Lanthanoid & Actinoids Contraction |
 57%
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Match the properties given in Column I with uses given in Column II 

Column I-(Property) Column II-(Metal)
A. An element that can show +8 oxidation state 1. Mn
B 3d block element that can show up to +7  2. Cr 
C 3d block element with the highest melting point 3. Os
4. Fe
 
A B C
1. 3 1 2
2. 1 2 3
3. 1 4 3
4. 4 2 3
Subtopic:  d-Block Elements- Properties & Uses |
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Match the statements given in Column I with the oxidation states given in Column and mark the correct option.

                Column I

              Column II

A. Oxidation state of Mn in MnO2 is

1. +2

2. +3

B. Most stable oxidation state of Mn is

3. +4

C. Most stable oxidation state of Mn in oxides is

4. +5

D. Characteristic oxidation state of lanthanoids is

5. +7

Codes
 

Options:   A    B    C    D  
1. 2 3 4 1
2. 3 1 5 2
3. 5 4 3 2
4. 4 5 3 2

         

Subtopic:  Lanthanoid & Actinoids Contraction |
 86%
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