Match the following : 

Elements Electronic configuration
i. 61 a. [Rn]5f136d0 7s 2
ii. 91 b. [Xe]4f56s2
iii. 101 c. [Rn]5f146d77s2
iv. 109 d. [Rn] 5f2 6d17s2
 
i ii iii iv
1. b d a c
2. c a d b
3. c d a b
4. a c b d

Subtopic:  d-Block Elements- Properties & Uses |
 85%
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Transition metals and their many compounds act as good catalysts due to :

1. Variable oxidation states 2. Unstable intermediate
3. Provide a suitable surface 4. All of the above
Subtopic:  d-Block Elements- Properties & Uses |
 82%
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Transition metals show paramagnetic behaviour due to:

1. Paired electrons in the (n-1) d-orbitals 2. Unpaired electrons in the (n-1) d-orbitals
3. Due to \(d^{10},\) and ​​​​​​​\(d^{0}\) configuration 4. None of the above

Subtopic:  d-Block Elements- Properties & Uses |
 93%
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Consider the following statements: 

a. Lanthanoid and actinoid belong to the f block and their general electronic configuration is  nf1-14 n-1d0-1ns2 .
b. All lanthanides and actinoids show an oxidation state of +3.
c. The magnetic properties of the actinoids are more complex than those of the lanthanoids. 
d. Lanthanoids are comparatively less electropositive than actinides

Correct statements amongst the above are:

1. a, b 2. c, d, a
3. d, a, b 4. b, c, d
Subtopic:  f-Block Elements- Properties & Uses |
 54%
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The correct statement(s) about interstitial compounds is/are:

1. Transition elements are large in size and contain multiple interstitial sites.
2. Transition elements can trap atoms of other elements.
3. Interstitial compounds are chemically inert.
4. All of the above.

Subtopic:  d-Block Elements- Properties & Uses |
 91%
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The spin-only magnetic moment of Ce3+ is -

1. 3.25 2. 1.73
3. zero 4. 4.21
Subtopic:  d-Block Elements- Properties & Uses |
 61%
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Match the following:

Ions  Number of unpaired electrons
i. Mn3+ a. 2
ii. Cr3+ b. 4
iii. V3+ c. 1
iv. Ti3+ d. 3
 
i ii iii iv
1. c d b a
2. b d a c
3. d b a c
4. b d c a
Subtopic:  d-Block Elements- Properties & Uses |
 80%
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In an aqueous solution, coloured ions would be:

1. Ti3+,V3+, Cu+

2. Sc3+, Mn2+, Fe3+

3. Ti3+,V3+, Mn2+, Fe3+,  Co2+

4. None of the above.

Subtopic:  d-Block Elements- Properties & Uses |
 76%
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The correct reactions among the following are:

a. MnO4-+H++Fe2+2Mn2++Fe3++H2O
b. C2O42-+MnO4-+H+Mn2++H2O+CO2
c. SO2+MnO4-+H+Mn2++H2O+SO3

1. a and c

2. b and c

3. a and b

4. a, b and c

Subtopic:  Chemistry of Mn and Cr Compounds |
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The correct statement(s) about transition elements are:  

1. +2, and +3 oxidation states are more common for elements in the first transition series, while higher oxidation states are more common for the heavier elements.
2. The heavier transition elements form low-spin complexes only.
3. The atomic sizes of the elements of the first transition series are smaller than those of the heavier elements (elements of 2nd and 3r transition series).
4. All of the above.
Subtopic:  d-Block Elements- Properties & Uses |
 87%
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