The respective oxidation states of P in H4P2O5, H4P2O6, and H4P2O7 are: 

1. +3, +5, and +4 2. +5, +3, and +4
3. +5, +4, and +3 4. +3, +4, and +5

Subtopic:  Group 15 - Preparation, Properties & Uses |
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AIPMT - 2010
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A solid (A) reacts with strong aqueous NaOH, liberating a foul smelling gas (B), which spontaneously burns in the air, giving smoky rings. A and B are, respectively:

1. P(red) and PH3 

2. P(white) and PH3

3. S8 and H2S

4. P(white) and H2S

Subtopic:  Group 15 - Preparation, Properties & Uses |
 78%
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Incorrect order among the following is:

1. F> Cl> Br> I2 Oxidising power
2. F < Cl > Br > I Electron gain enthalpy
3. F> Cl> Br> I2 Bond dissociation energy
4. F> Cl > Br > I Electronegativity

Subtopic:  Group 17 - Preparation, Properties & Uses |
 78%
From NCERT
AIPMT - 2008
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The number of \(\mathrm{S=O}\) bonds present in \(\mathrm{H}_2\mathrm{S}_2 \mathrm{O}_8\) is:

1. 1 2. 2
3. 3 4. 4
Subtopic:  Group 16 - Preparation, Properties & Uses |
 81%
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A balanced chemical equation for the reaction showing catalytic oxidation of NH3 by atmospheric oxygen is:

1. 4NH3 + \(\underset{\text{From air}}{5O_2} \)   \(\xrightarrow[\text{500 K; 9 bar}]{\text{Pt / Rh gauge catalyst}}\)   4NO + 6H2O
2. 3NH4 + \(\underset{\text{From air}}{5O_2} \)  \(\xrightarrow[\text{500 K; 9 bar}]{\text{Pt / Rh gauge catalyst}}\)  3NO + 6H2O
3. 4NH3 + \(\underset{\text{From air}}{5O_2} \)  \(\xrightarrow[\text{cold}]{\text{no catalyst}}\)  4NO + 6H2O
4. 3NH4 + \(\underset{\text{From air}}{5O_2} \)  \(\xrightarrow[\text{cold}]{\text{no catalyst}}\)  3NO + 6H2O
Subtopic:  Group 15 - Preparation, Properties & Uses |
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The correct structure of pyrophosphoric acid is:

1. 2.
3. 4.
Subtopic:  Group 15 - Preparation, Properties & Uses |
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PH3 forms bubbles when passed slowly through water but NH3 gets dissolved in water, because: 

1. NH3 forms an H-bond with water, so it is soluble but PH3 does not form an H-bond.
2. NH3 does not form an H-bond with water, so it is soluble but PH3 does form an H-bond.
3. NH3 and PHboth form H-bond with water. 
4. NH3 and PHboth do not form H-bond with water.

Subtopic:  Group 15 - Preparation, Properties & Uses |
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The disproportionation reaction of H3PO3 is as follows:

H3PO3  X + Y

 X and Y in the above reaction are:

1. H3PO2, HPO2  

2. H3PO4, PH3

3. H2PO6, PO3

4. None of the above.

Subtopic:  Group 15 - Preparation, Properties & Uses |
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The correct increasing order of basic strength of hydrides:

1. BiH3 \(\simeq \) SbH3 < AsH3 < PH3 < NH3 
2. BiH3  > NH3  > PH3 > SbH3 > AsH3 
3. SbH3 < AsH3 < PH3 < NH3 < BiH3 
4. AsH3 > NH3 > PH3 > SbH3 > BiH3

Subtopic:  Group 15 - Preparation, Properties & Uses |
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The compound among the following with the lowest pKa value is?

1. H2O

2. H2S

3. H2Se

4. H2Te

Subtopic:  Group 16 - Preparation, Properties & Uses |
 75%
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