In the preparation of compounds of Xe, Bartlett had taken O2+PtF6- as a base compound. This is because-

1. Both Oand Xe have the same size.
2. Both O2  and Xe have the same electron gain enthalpy.
3. Both O2 and Xe have almost the same ionisation enthalpy.
4. Both Xe and O2 are gases.

Subtopic:  Group 18 - Preparation, Properties & Uses |
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In solid-state, PCl5 exists as: 

1. Covalent solid.
2. Octahedral structure.
3. Ionic solid with [PCl6]+ octahedral and [PCl4]- tetrahedral.
4. Ionic solid with [PCl4]+ tetrahedral and  [PCl6]- octahedral.

Subtopic:  Group 15 - Preparation, Properties & Uses |
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Reduction potentials of some ions are given below. Arrange them in decreasing order of oxidising power.

Ion

ClO4- IO4- BrO4-

Reduction potential E- /V

= 1.19V

= 1.65V

= 1.74V

1.  ClO4- > IO4- > BrO4-
2.  IO4- > BrO4- > ClO4-
3.  BrO4- > IO4- > ClO4-
4.  BrO4- > ClO4- >  IO4- 

Subtopic:  Group 17 - Preparation, Properties & Uses |
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Which of the following is isoelectronic pair?

1. ICl2 , ClO2

2. BrO2- , BrF2+

3. ClO2 , BrF

4. CN- , O3

Subtopic:  Group 17 - Preparation, Properties & Uses | Group 16 - Preparation, Properties & Uses |
 72%
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If chlorine gas is passed through a hot NaOH solution, two changes are observed in the oxidation number of chlorine during the reaction. These are ......... and  .............

a. 0 to +5

b. 0 to +3

c. 0 to -1

d. 0 to +1

Choose the correct option

1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)

Subtopic:  Group 17 - Preparation, Properties & Uses |
 67%
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Which of the following options are not in accordance with the property mentioned against them?

a. F2 > Cl2 > Br2 > I2                                   Oxidising power

b. MI > MBr > MCI > MF                            lonic character of metal halide

c. F2 >Cl2 > Br2 > I2                                     Bond dissociation enthalpy

d. HI < HBr < HCl < HF                               Hydrogen-halogen bond strength

1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Group 17 - Preparation, Properties & Uses |
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Which of the following is correct for P4 molecule of white phosphorus?

a. It has 6 lone pairs of electrons

b. It has six P — P single bonds

c. It has three P — P single bonds

d. It has four lone pairs of electrons

Choose the correct option

1. (a, b)
2. (b, c)
3. (c, d)
4. (b, d)

Subtopic:  Group 15 - Preparation, Properties & Uses |
 67%
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Which of the following statements are correct?

a. Among halogens, the radius ratio between iodine and fluorine is maximum.
b. Leaving F — F bond, all halogens have weaker X — X bond than X — X' bond in interhalogens.
c. Among interhalogen compounds a maximum number of atoms are present in iodine fluoride.
d. Interhalogen compounds are more reactive than halogen compounds.

1. (a, b, c)
2. (b, c, d)
3. (a, c, d)
4. (a, b, d)

Subtopic:  Group 17 - Preparation, Properties & Uses |
 69%
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Which of the following statements are correct for SO2 gas?        

a. It acts as a bleaching agent in moist conditions.

b. Its molecule has linear geometry.

c. Its dilute solution is used as a disinfectant.

d. It can be prepared by the reaction of dilute H2SO4 with metal sulphide.

1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)

Subtopic:  Group 16 - Preparation, Properties & Uses |
 64%
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Which of the following statements are correct?

a. All the three N – O bond lengths in HNO3 are equal.
b. All P – Cl bond lengths in PCl5 molecule in the gaseous state are equal.
c. P4 molecule in white phosphorus have angular strain therefore white phosphorus is very reactive.
d. PCl5 is ionic in a solid-state in which cation is tetrahedral and the anion is octahedral.

Choose the correct option


1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Group 16 - Preparation, Properties & Uses | Group 15 - Preparation, Properties & Uses |
 80%
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