Which of the following has a negative slope?

       

1. C → CO

2. Fe → Fe2O3

3. Mg → MgO

4. All of the above

Subtopic:  Ellingham Diagram |
 68%
Level 2: 60%+
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During extraction, copper is obtained by the reduction of cupric oxide with:

1. Cu2S

2. SO2

3. FeS

4. CO

Subtopic:  Intro - Flux, Leaching, Roasting & Calcination |
 71%
Level 2: 60%+
NEET - 2012
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A pair of metals among the following that can be purified by the van Arkel method are:

1. Zr,  and Ti

2. Ag, and Au

3. Ni,  and Fe

4. Ga, and In

Subtopic:  Metallurgy of individual elements | Refining Process |
 93%
Level 1: 80%+
NEET - 2011
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Consider the following reactions at 1000 oC.

(I) ZnS + 1/2O2(g)  \(\xrightarrow[]{\Delta }\)  ZnO(g);  ∆Go = -360 kJ mol-1
(II) Cs + 1/2O2(g)  \(\xrightarrow[]{\Delta }\) CO(g); ∆Go = -460 kJ mol-1  

Choose the correct statement about the above reactions at 1000 oC:

1. ZnO is more stable than CO

2. ZnO can be reduced to Zn by C

3. ZnO, and CO are formed at an equal rate

4. ZnO can not be reduced to Zn by C

Subtopic:  Ellingham Diagram | Metallurgy of individual elements |
 72%
Level 2: 60%+
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What is the composition of the anode mud used in the electrolytic refining of silver?

1. Zn, Cu, Ag, Au

2. Zn, Ag, Au

3. Cu, Ag, Au

4. Au only

Subtopic:  Intro - Flux, Leaching, Roasting & Calcination |
Level 3: 35%-60%
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Incorrect statement for the Hall-Heroult process is:

1. Cryolite  Na3AlF6  lower the melting point of  Al2O3, and increase its electrical conductivity.
2. Al is obtained at the cathode, and CO2 at the anode.
3. Li2CO3 can be used in place of cryolite(Na3AIF6)
4. MgF2  can be used in place of fluorspar (CaF2)

Subtopic:  Intro - Flux, Leaching, Roasting & Calcination |
Level 4: Below 35%
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The method of purification that is represented by the following equation is:
\(Ti(s) \ + \ 2I_{2}(g) \ \xrightarrow[]{523 \ K} \ TiI_{4}{g}\)
\(TiI_{4}(g)\ \xrightarrow[]{1700 \ K} \ Ti(s) \ + \ 2I_{2}(g)\)

1. Cupellation

2. Poling

3. Van Arkel

4. Zone refining

Subtopic:  Refining Process |
 91%
Level 1: 80%+
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The correct statement among the following is: 

1. In the decomposition of oxide into oxygen and gaseous metal, entropy increases.
2. Decomposition of oxide is an endothermic change.
3. To make ∆G° negative, the temperature should be high enough so that T∆S° > ∆H°.
4. All of the above.

Subtopic:  Ellingham Diagram |
 86%
Level 1: 80%+
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The chemical composition of "slag" formed during the smelting process in the extraction of copper is:

1. Cu+ FeS                                    

2. FeSiO3

3. CuFeS                                         

4. Cu2S + FeO

Subtopic:  Intro - Flux, Leaching, Roasting & Calcination |
 80%
Level 1: 80%+
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Aluminium is extracted from alumina Al2O3 by electrolysis of a molten mixture of:

1. Al2O3+HF+NaAlF4

2. Al2O3+CaF2+NaAlF4

3. Al2O3+Na3AlF6+CaF2

4. Al2O3+KF+Na3AlF6

Subtopic:  Intro - Flux, Leaching, Roasting & Calcination | Metallurgy of individual elements |
 77%
Level 2: 60%+
AIPMT - 2012
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