If a reaction A + B → C is exothermic to the extent of 30 kJ mol−1 and the forward reaction has an activation energy of 249 kJ mol−1, the activation energy for the reverse reaction in kJ mol-1 will be:

1. 324 2. 279
3. 40 4. 100
Subtopic:  Arrhenius Equation |
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For a reaction A → B, the Arrhenius equation is given as  \(log_{e}k \ = \ 4 \ - \ \frac{1000}{T}\) the activation energy in J/mol for the given reaction will be:

1. 8314

2. 2000

3. 2814

4. 3412

Subtopic:  Arrhenius Equation |
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The rate constant, the activation energy, and the Arrhenius parameter of a chemical reaction at 25°C are 3.0×10-4 s-1104.4 kJ mol-1 and 6.0×1014s-1 respectively.
The value of the rate constant as T → ∞ will be:

1. 2.0 × 1018 s-1                                                  

2. 6.0 × 1014 s-1

3.                                                                    

4. 3.6 × 1030 s-1

Subtopic:  Arrhenius Equation |
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For A + B → C + D, H = -20 kJ mol-1 , the activation energy of the forward reaction is 85 kJ mol-1. The activation energy for the backward reaction is…. kJ mol-1.

1. 105 2. 85
3. 40 4. 65
Subtopic:  Arrhenius Equation |
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The decomposition of hydrocarbons follows the equation: k = (4.5 × 1011s–1) e-28000K/T

The activation energy (Ea) for the reaction would be:

1. 232.79 kJ mol-1 2. 245.86 kJ mol-1
3. 126.12 kJ mol-1 4. 242.51 kJ mol-1
Subtopic:  Arrhenius Equation |
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In a first-order reaction A  products, the concentration of the reactant decreases to 6.25 % of its initial value in 80 minutes. The value of the rate constant, if the initial concentration is 0.2 mole/litre, will be:

1. 2.17 × 10-2 min-1

2. 3.46 × 10-2 min-1

3. 3.46 × 10-3min-1

4. 2.16 × 10-3 min-1

Subtopic:  Arrhenius Equation |
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The rate of a reaction doubles when its temperature changes from 300 K to 310 K. The activation energy of such a reaction will be:

 \((R=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1} \text { and } \log 2=0.301)\)

1. \(53.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \) 2. \(68.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \)
3. \(59.5 \mathrm{~kJ} \mathrm{~mol}^{-1} \) 4. \(70.5 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

Subtopic:  Arrhenius Equation |
 70%
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If a reaction A + B  C is exothermic to the extent of 30 kJ/mol and the forward reaction has an activation energy of 70 kJ/mol, the activation energy for the reverse reaction will be:

1. 30 kJ/mol                                       

2. 40kJ/mol

3. 70 kJ/mol                                       

4. 100 kJ/mol

Subtopic:  Arrhenius Equation |
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The rate constant for a chemical reaction that takes place at 500 K is expressed as K = A e-1000. The activation energy of the reaction will be:

1. 100 cal/mol

2. 1000 kcal/mol

3. 104 kcal/mol

4. 106 kcal/mol

Subtopic:  Arrhenius Equation |
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The correct graphical representation of relation between ln k and 1/T is:

1.  2.
3. 4.
Subtopic:  Arrhenius Equation |
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