For a reaction of the type 2A + B  2C, the rate of the reaction is given by kA2B. When the volume of the reaction vessel is reduced to 14 th of the original volume, the rate of reaction changes by a factor of -

1. 0.25                                                          

2. 16

3. 64                                                             

4. 4

Subtopic:  Definition, Rate Constant, Rate Law | First Order Reaction Kinetics |
 75%
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If a reaction A + B → C is exothermic to the extent of 30 kJ mol−1 and the forward reaction has an activation energy of 249 kJ mol−1, the activation energy for the reverse reaction in kJ mol-1 will be:

1. 324 2. 279
3. 40 4. 100
Subtopic:  Arrhenius Equation |
 93%
From NCERT
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Select the correct option based on statements below:

Assertion (A): For elementary reactions, the law of mass action and the rate of law expression are generally the same.
Reason (R): The molecularity of an elementary reaction is always one.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Order, Molecularity and Mechanism |
 64%
From NCERT
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The rate of a reaction doubles when its temperature changes from 300 K to 310 K. The activation energy of such a reaction will be:

 \((R=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1} \text { and } \log 2=0.301)\)

1. \(53.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \) 2. \(68.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \)
3. \(59.5 \mathrm{~kJ} \mathrm{~mol}^{-1} \) 4. \(70.5 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

Subtopic:  Arrhenius Equation |
 70%
From NCERT
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For a reaction A → B, the Arrhenius equation is given as  \(log_{e}k \ = \ 4 \ - \ \frac{1000}{T}\) the activation energy in J/mol for the given reaction will be:

1. 8314

2. 2000

3. 2814

4. 3412

Subtopic:  Arrhenius Equation |
 77%
From NCERT
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The rate constant for a first-order reaction is 4.606×10-3 s-1. The time required to reduce 2.0 g of the reactant to 0.2 g will be:

1. 200 s 2. 500 s
3. 1000 s 4. 100 s
Subtopic:  First Order Reaction Kinetics |
 85%
From NCERT
NEET - 2020
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For a general reaction A  B, the plot of the concentration of A vs. time is given in the figure.
 

The slope of the curve will be:

1. -k 2. -k/2
3. -k2 4. -k/3
Subtopic:  Definition, Rate Constant, Rate Law |
 89%
From NCERT
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For the reaction, \(2 A+B \rightarrow 3 C+D\)

An incorrect expression for the rate of reaction is:

1. \(-\frac{d[C]}{3} d t \) 2. \(-\frac{d[B]}{d t} \)
3. \(\frac{d[D]}{d t} \) 4. \(-\frac{d[A]}{2 d t}\)
Subtopic:  Definition, Rate Constant, Rate Law |
 90%
From NCERT
AIPMT - 2006
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The decomposition of hydrocarbons follows the equation: k = (4.5 × 1011s–1) e-28000K/T

The activation energy (Ea) for the reaction would be:

1. 232.79 kJ mol-1 2. 245.86 kJ mol-1
3. 126.12 kJ mol-1 4. 242.51 kJ mol-1
Subtopic:  Arrhenius Equation |
 73%
From NCERT
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The role of a catalyst is to change: 

1. Gibbs energy of the reaction

2. Enthalpy of reaction

3. The activation energy of the reaction 

4. Equilibrium constant

Subtopic:  Catalyst |
 94%
From NCERT
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