A reaction having equal energies of activation for forward and reverse reaction has:

1. ΔG = 0

2. ΔH = 0

3. ΔH = ΔG = ΔS = 0

4. ΔS = 0

Subtopic:  Arrhenius Equation |
 72%
From NCERT
AIPMT - 2013
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In a reaction, A + B  → Product, the rate is doubled when the concentration of B is doubled, and the rate increases by a factor of 8, when the concentrations of both the reactants (A and B) are doubled. The rate law for the reaction can be written as:

1. Rate = k[A][B]2

2. Rate = k[A]2[B]2

3. Rate = k[A][B]

4. Rate = k[A]2[B]

Subtopic:  Definition, Rate Constant, Rate Law |
 75%
From NCERT
AIPMT - 2012
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In a zero-order reaction for every 10 ° rise of temperature, the rate is doubled.
If the temperature is increased from 10 °C to 100 °C,
the rate of the reaction will become:

1. 256 times

2. 512 times

3. 64 times

4. 128 times

Subtopic:  First Order Reaction Kinetics |
 84%
From NCERT
AIPMT - 2012
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The incorrect statement regarding the order of reaction is:

1. Order is not influenced by the stoichiometric coefficient of the reactants.
2. Order of reaction is the sum of power to the concentration terms of reactants to express the rate of reaction.
3. The order of reaction is always a whole number.
4. Order can be determined by experiments only.
Subtopic:  Definition, Rate Constant, Rate Law |
 79%
From NCERT
AIPMT - 2011
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For the reaction, 
N2O5g2NO2g+12O2g
the value of rate of disappearance of N2Ois given as 6.25 x 10-3mol L-1s-1.The rate of formation of NO2 and O2 is given respectively as:
 

1. 6.25 × 10-3 mol  L-1s-1 and 6.25 × 10-3 mol  L-1s-1.
2. 1.25 × 10-2 mol  L-1s-1 and 3.125 × 10-3 mol  L-1s-1.
3. 6.25 × 10-3 mol  L-1s-1 and 3.125 × 10-3 mol  L-1s-1.
4. 1.25 × 10-2 mol  L-1s-1 and 6.25 × 10-3 mol  L-1s-1.
Subtopic:  Order, Molecularity and Mechanism |
 87%
From NCERT
AIPMT - 2010
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For an endothermic reaction, the energy of activation is Ea, and the enthalpy of reaction is ΔH (both of these in kJ/mol). The minimum value of Ea will be:

1. Less than H

2. Equal to H

3. More than H

4. Equal to zero

Subtopic:  Arrhenius Equation |
 62%
From NCERT
AIPMT - 2010
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During the kinetic study of the reaction, 2A + B\( \rightarrow\)C + D, following results were obtained:
 

Run

[A)/ mol L-1

[B)/ mol L-1

Initial rate of
formation of D/mol 

L-1

I

0.1

0.1

6.0×10-3

II

0.3

0.2

7.2×10-2

III

0.3

0.4

2.88×10-1

IV

0.4

0.1

2.40×10-2


Based on the above data which one of the following is correct?

1. rate= k[A]2[B]

2. rate= k[A][B]

3. rate= k[A]2[B]2

4. rate= k[A][B]2

Subtopic:  Definition, Rate Constant, Rate Law |
 76%
From NCERT
AIPMT - 2010
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The half-life period of a first-order reaction is 1386 s. The specific rate constant of the reaction is:

1. 5.0×10-3s-1

2. 0.5×10-2s-1

3. 0.5×10-3s-1

4. 5.0×10-2s-1

Subtopic:  Definition, Rate Constant, Rate Law |
 84%
From NCERT
AIPMT - 2009
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For the reaction, A + B → products, it is observed that-
(1) On doubling the initial concentration of A only, the rate of reaction is also doubled and 
(2) On doubling the initial concentrations of both A and B, there is a change by a factor of 8 in the rate of the reaction. 
The rate of this reaction is given by:

1. rate=k [A]2[B]

2. rate=k [A][B]2

3. rate=k [A]2[B]2

4. rate=k [A][B]

Subtopic:  Definition, Rate Constant, Rate Law |
 84%
From NCERT
AIPMT - 2009
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For the reaction, \(\mathrm{N}_2+3 \mathrm{H}_2 \rightarrow 2 \mathrm{NH}_3,\) if, \(\frac{d[NH_{3}]}{dt} \ = \ 2\times 10^{-4} \ mol \ L^{-1} \ s^{-1}\), the value of  \(\frac{-d[H_{2}]}{dt}\) would be:

1. \(3 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \) 2. \(4 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \)
3. \(6 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \) 4. \(1 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}\)
Subtopic:  Definition, Rate Constant, Rate Law |
 84%
From NCERT
AIPMT - 2009
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