Q. No.The value of E0 cell for the following reaction is:
\(Cu^{2+}+ Sn^{2+}\to Cu +Sn^{4+ } \)
(Given, equilibrium constant is 106)
1.
0.17
2.
0.01
3.
0.05
4.
1.77
\(Cu^{2+}+ Sn^{2+}\to Cu +Sn^{4+ } \)
On the basis of the information available from the reaction:
The minimum e.m.f. required to carry out the electrolysis of Al2O3 is:
(F = 96500 C mol–1)
1. 2.14 V
2. 4.28 V
3. 6.42 V
4. 8.56 V
Mg(s) + 2Ag+(0.0001M) → Mg2+(0.130M) + 2Ag(s)
If EƟ(cell) for the above mentioned cell is 3.17 V, then E(cell) value will be-
(log 13=1.1)
1. 2.87 V
2. 3.08 V
3. 2.96 V
4. 2.68 V
Resistance of a conductivity cell filled with 0.1 mol L–1 KCl solution is 100 Ω. If the resistance of the same cell when filled with 0.02 mol L–1 KCl solution is 520 Ω. The conductivity of 0.1 mol L–1 KCl solution is 1.29 S/m. The molar conductivity of 0.02 mol L–1 KCl solution is-
1. 134 S cm2 mol–1
2. 124 S cm2 mol–1
3. 144 S cm2 mol–1
4. 154 S cm2 mol–1
In a typical fuel cell, the reactants (R) and products (P) are:
| 1. | R = H2(g), O2(g); P = H2O2(l) |
| 2. | R = H2(g), O2(g); P = H2O(l) |
| 3. | R = H2(g), O2(g), C l2(g); P = HClO4(aq) |
| 4. | R = H2(g), N2(g); P = NH3(aq) |
Aluminium oxide may be electrolysed at 1000 °C to furnish aluminium metal.
The cathode reaction is Al3+ + 3e- → Al.
To prepare 5.12 kg of aluminium metal by this method would require:
(Atomic mass = 27 amu; 1 faraday=96,500 Coulombs)
1. 5.49×101 C of electricity
2. 5.49×104 C of electricity
3. 1.83×107 C of electricity
4. 5.49×107 C of electricity
Given below are two statements:
| Assertion (A): | Cu is less reactive than hydrogen. |
| Reason (R): | E°Cu2+/ Cu is negative. |
| 1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | (A) is false but (R) is true. |
Match Column-I (Types of cell) with Column-II (Characteristics shown by cells ) and mark the appropriate option:
| Column I (Type of cell) |
Column II (Characteristics) |
||
| A | Lechlanche cell | 1. | Cell reaction 2H2 +O2 → 2H2O |
| B | Ni-Cd cell | 2. | Does not involve any ion in solution and is used in hearing aids. |
| C | Fuel cell | 3. | Rechargeable |
| D | Mercury cell | 4. | -Reaction at anode, Zn → Zn2+ + 2e- |
Codes:
| Options: | A | B | C | D |
| 1. | 2 | 3 | 4 | 1 |
| 2. | 4 | 3 | 1 | 2 |
| 3. | 1 | 4 | 3 | 2 |
| 4. | 4 | 1 | 3 | 2 |
The most stable oxidized species among the following is:
\(E_{{\mathrm{Cr}_2 \mathrm{O}_7^2}/ \mathrm{Cr}^{3+}}^{o} =1.33 \mathrm{~V} ; E_{\mathrm{Cl}_2 / \mathrm{Cl}^{-}}^{o}=1.36 \mathrm{~V} \)
\( E_{\mathrm{MnO_{4}}^{-} / \mathrm{Mn}^{2+}}^{o}=1.51 \mathrm{~V} ; E_{\mathrm{Cr}^{3+} / \mathrm{Cr}}^{o}=-0.74 \mathrm{~V}\)
| 1. | Cr3+ | 2. | MnO4- |
| 3. | Cr2O72- | 4. | Mn2+ |
The incorrect statement about the solution of electrolytes is:
| 1. | Conductivity of solution depends upon the size of ions. |
| 2. | Conductivity depends upon the viscosity of solution. |
| 3. | Conductivity does not depend upon the solvation of ions present in solution. |
| 4. | Conductivity of solution increases with temperature. |
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