When 0.1 mol MnO42– is oxidized, the quantity of electricity required to completely oxidise MnO42– to MnO4 is:

1. 96500 C

2. 2 × 96500 C

3. 9650 C

4. 96.50 C

Subtopic:  Faraday’s Law of Electrolysis |
 77%
From NCERT
AIPMT - 2014
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A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl of pH = 10 and by passing hydrogen gas around the platinum wire at one atm pressure. The oxidation potential of the electrode would be: 

1. 0.59 V 2. 0.118 V
3. 1.18 V 4. 0.059 V
Subtopic:  Relation between Emf, G, Kc & pH |
 74%
From NCERT
AIPMT - 2013
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A button cell used in watches functions as following
Zn(s) + Ag2O(s) + H2O(l) \(\rightleftharpoons\) 2Ag(s) + Zn2+(aq) + 2OH(aq)
If half-cell potentials are-

Zn2+(aq) + 2e→ Zn(s)  Eo = – 0.76 V 
Ag2O(s) + H2O(l) + 2e → 2Ag(s) + 2OH(aq) Eo = 0.34 V

The cell potential will be:

1. 0.42 V 2. 0.84 V
3. 1.34 V 4. 1.10 V
Subtopic:  Electrode & Electrode Potential |
 86%
From NCERT
AIPMT - 2013
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Based on electrode potentials in the table below: 
Cu2+(aq) + e- → Cu+(aq) 0.15 V
Cu+(aq) + e- → Cu(s) 0.50 V

The value of \(E_{Cu^{2+}/Cu}^{o}\) will be:
1. 0.325 V 2. 0650 V
3. 0.150 V 4. 0.500 V
Subtopic:  Electrode & Electrode Potential |
 60%
From NCERT
AIPMT - 2011
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For the reduction of silver ions with copper metal, the standard cell potential was found to be +0.46 V at 25 °C. The value of standard Gibbs energy, ΔGo will be: 

(F = 96500 C mol-1)

1. -89.0 kJ

2. -89.0 J

3. -44.5 kJ

4. -98.0 kJ

Subtopic:  Faraday’s Law of Electrolysis |
 69%
From NCERT
AIPMT - 2010
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Al2Ois reduced by electrolysis at low potentials and high currents. If 4.0 x 10A of current is passed through molten Al2O3 for 6 hours, the mass of aluminum produced is: (Assume 100 % current efficiency, the atomic mass of Al = 27 g mol-1)

1. 9.0 x 103 g 2. 8.1 x 104 g
3. 2.4 x 105 g 4. 1.3 x 104 g
Subtopic:  Faraday’s Law of Electrolysis |
 65%
From NCERT
AIPMT - 2009
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The molar conductance of M32 solution of a weak monobasic acid is 8.0 ohm-1 cmand at infinite dilution is 400 ohm-1 cm2. The dissociation constant of this acid is: 

1. \(1.25 \times10^{-5}\) 2. \(1.25 \times10^{-6}\)
3. \(6.25 \times10^{-4}\) 4. \(1.25 \times10^{-4}\)
Subtopic:   Kohlrausch Law & Cell Constant |
 64%
From NCERT
AIPMT - 2009
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Given:
(i) Cu2++2e-Cu    Eo = 0.337 V 
(ii) Cu2++e-Cu+  Eo = 0.153 V 
Electrode potential, Eo for the reaction, 
Cu++e-Cu, will be: 

1. 0.52 V

2. 0.90 V

3. 0.30 V

4. 0.38 V

Subtopic:  Relation between Emf, G, Kc & pH |
 75%
From NCERT
AIPMT - 2009
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Kohlrausch's law states that at:

1. Finite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.
2. Infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte depending on the nature of the other ion of the electrolyte.
3. Infinite dilution, each ion makes definite contribution to conductance of an electrolyte whatever be the nature of the other ion of the electrolyte.
4. Infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.
Subtopic:   Kohlrausch Law & Cell Constant |
 53%
From NCERT
AIPMT - 2008
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The correct order of ionic mobility of ions in an aqueous solution is:
1. K+> Na+> Rb+> Cs+
2. Cs+> Rb+> K+> Na+
3. Rb+> K+> Cs+> Na+
4. Na+> K+> Rb+> Cs+
Subtopic:  Relation between Emf, G, Kc & pH |
 75%
From NCERT
AIPMT - 2008
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