The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol individually. The mixture shows:

1. No deviation from Raoult's law

2. Positive deviation from Raoult's law

3. Negative deviation from Raoult's law

4. That the solution is unsaturated

A pair of  isotonic solutions, among the following, is (assuming temperature to be the same) :

1. 0.1 (M) urea and 0.1 (M) NaCl

2. 0.1 (M) urea and 0.2 (M) MgCl₂

3. 0.1 (M) NaCl and 0.1 (M) Na₂SO₄

4. 0.1 (M) Ca(NO₃)₂ and 0.1 (M) Na₂SO₄

The correct statement regarding a solution of two components A and B exhibiting positive deviation from ideal behaviour is :

A 500 g toothpaste sample has 0.4 g fluoride concentration. The fluoride concentration in terms of ppm will be -

The freezing point of depression constant (K_f ) of benzene is 5.12 K kg mol^–1. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is-
(rounded off upto two decimal places):
1. 0.80 K
2. 0.40 K
3. 0.60 K
4. 0.20 K

The azeotropic mixture of water and ethanol boils at 78.15 ^oC. When this mixture is distilled, it is possible to obtain-

1. Pure H₂O

2. Pure C₂H₅OH

3. Pure H₂O as well as pure C₂HOH

4. Neither H₂O nor C₂H₅OH in their pure state 

Preservation of fruits against bacterial action by adding sugar is an example of-

1. Exosmosis

2. Reverse-osmosis

3. Diffusion

4. Capillary action

The mixture among the following that forms maximum boiling azeotrope is:

1. Heptane + Octane
2. Water + Nitric acid
3. Ethanol + Water
4. Acetone + Carbon disulphide

1.00 g of non-electrolyte solute (molar mass 250 g mol^-1) was dissolved in 51.2 g of benzene. If the freezing point depression constant, K_f of benzene is 5.12 mol^-1 kg K, the freezing point of benzene will be lowered by:

1. 0.4 K

2. 0.3 K

3. 0.5 K

4. 0.2 K

A solution containing 10 g/dm³ of urea (molecular mass = 60 g mol^-1) is isotonic with a 5 % solution of a non-volatile solute. The molecular mass of this non-volatile solute is: