Select the correct option based on statements below:

Assertion (A): Semiconductors are solids with conductivities in the range from 10-6 — 10ohm-1 m-1.
Reason (R): Intermediate conductivity in semiconductors is due to a partially filled valence band.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Imperfections in Solids & Semiconductors |
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Select the correct option based on statements below:

Assertion (A): The packing efficiency is maximum for the fcc structure.
Reason (R): The coordination number is 12 in fcc structure.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Density & Packing Fraction |
 52%
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Select the correct option based on statements below:

Assertion (A): Total number of octahedral voids present in the unit cell of cubic close packing including the one that is present at the body center, is four.
Reason (R): Besides the body center there is one octahedral void present at the center of each of the six faces of the unit cell and each of which is shared between two adjacent unit cells.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Voids, Radius Ratio & Coordination Number |
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Select the correct option based on statements below:

Assertion (A): Graphite is a good conductor of electricity. However, diamond belongs to the category of insulators.
Reason (R): Graphite is soft in nature whereas diamond is very hard and brittle.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Introduction & Crystal System |
 67%
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Select the correct option based on statements below:
Assertion (A): The total number of atoms present in a simple cubic unit cell is one.
Reason (R): Simple cubic unit cell has atoms at its corners, each of which is shared between eight adjacent unit cells.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.
Subtopic:  Introduction & Crystal System |
 86%
From NCERT
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Match the type of packing given in Column I with the items given in Column II.

Column I Column II
A. Square close packing in two dimensions 1. Triangular voids
B. Hexagonal close packing in two dimensions 2. Pattern of spheres is repeated in every fourth layer
C. Hexagonal close packing in three dimensions 3. Coordination number = 4
D. Cubic close packing in three dimensions 4. Pattern of sphere is repeated in alternate layers

Codes

A B C D
1. 3 2 4 1
2. 1 2 3 4
3. 3 1 4 2
4. 4 1 3 2
Subtopic:  Voids, Radius Ratio & Coordination Number |
 66%
From NCERT
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Match the items given in Column I with the items given in Column II.

Column I Column II
A. Mg in solid state 1p-type semiconductor
B. MgCl2 in molten state 2n-type semiconductor
C. Silicon with phosphorus 3. Electrolytic conductors
D. Germanium with boron 4. Electronic conductors

Codes

A B C D
1. 2 3 4 1
2. 1 2 3 4
3. 1 4 3 2
4. 4 3 2 1

Subtopic:  Imperfections in Solids & Semiconductors |
 86%
From NCERT
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Match the types of defects given in Column I with the statement given in Column II.

Column I Column II
A. Impurity defect 1. NaCl with anionic sites called F-centres
B. Metal excess defect 2. FeO with Fe3+
C. Metal deficiency defect 3. NaCl with Sr2+ and some cationic sites vacant

Codes

A B C
1. 2 3 1
2. 3 1 2
3 1 2 3
4. 2 1 3
Subtopic:  Imperfections in Solids & Semiconductors |
 73%
From NCERT
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Match the type of unit cell given in Column I with the features given in Column II.
 

Column I Column II
A Primitive cubic unit cell 1. Each of the three perpendicular edges compulsorily have the different edge length i.e., a ≠ b ≠ c
B Body centred cubic unit cell  2. Number of atoms per unit cell is one.
C Face centred cubic unit cell  3. Each of the three perpendicular edges compulsorily have the same edge length i.e., a=b=c
D End centred orthorhombic  4. In addition to the contribution from the corner unit cell atoms the number of atoms present in a unit cell is one
5. In addition to the contribution from the corner atoms the number of atoms present in a unit cell is three

Codes:

Options:  A   B   C   D 
1.  2,5   3,1   4,2  1,3
2. 1 2 3 5
3.  2,3  3,4 3,5 1,4
4.  4  5  3 2

Subtopic:  Introduction & Crystal System |
 80%
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Match the defects given in Column I with the statements given in Column II.

Column I Column II
A. Simple vacancy defect 1. Shown by non-ionic solids and increases the density of the solid
B. Simple interstitial defect 2. Shown by ionic solids and decreases the density of the solid
C. Frenkel defect 3. Shown by non-ionic solids and decreases the density of the solid
D. Schottky defect 4. Shown by ionic solids and density of the solid remains the same

Codes

A B C D
1. 3 1 4 2
2. 1 2 3 4
3. 1 4 3 2
4. 4 1 3 2

Subtopic:  Imperfections in Solids & Semiconductors |
 82%
From NCERT
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