The numbers of structural isomers of ${\mathrm{C}}_4{\mathrm{H}}_8$ (with one double bond) and ${\mathrm{C}}_5{\mathrm{H}}_8$ (with one triple bond) are:

1. ${\mathrm{C}}_4{\mathrm{H}}_8 = 3 ; {\mathrm{C}}_5{\mathrm{H}}_8 = 3$

2. ${\mathrm{C}}_4{\mathrm{H}}_8 = 4 ; {\mathrm{C}}_5{\mathrm{H}}_8 = 4$

3. ${\text{C}}_4{\mathrm{H}}_8 = 3 ; {\mathrm{C}}_5{\mathrm{H}}_8 = 4$

4.${\mathrm{C}}_4{\mathrm{H}}_8 = 4 ; {\mathrm{C}}_5{\mathrm{H}}_8 = 3$

The balanced chemical equation for the combustion reaction of Butane is :

Lewis acid(s) that can be used during the ethylation of benzene is/are:

1. ${\mathrm{FeCl}}_3$

2. ${\mathrm{SnCl}}_4$ 

3. ${\mathrm{BF}}_3$

4. All of the above

Out of benzene, m–dinitrobenzene and toluene, the one that will undergo nitration most easily is -

1. Benzene

2. m–Dinitrobenzene

3. Toluene

4. None of these

Benzene is extraordinarily stable, though it contains three double bonds, because of -

1. Delocalized protons

2. Delocalized neutrons

3. Resonance

4. None of these

Propanal and pentane-3-one are the products of ozonolysis of an alkene. The structural formula of the alkene is  :

1.		2.	,
3.		4.

An alkene ‘A’ contains 3 C – Cσ bonds, 8 C – H σ bonds, and 1 C – C π bond,

 ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. The IUPAC name of ‘A’ is -

1. Prop-2-yne

2. But-2-ene

3. But-2-yne

4. Prop-2-ene

 An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one.
The IUPAC name of ‘A’ is :

1. 3-Ethylpent-2-ene

2. 3-Ethylpent-2- yne

3. 2-Ethylpent-3-ene

4. 3-Ethylpent-4-yne

The products of ozonolysis of 1,2-dimethyl benzene (o-xylene) are -

1. Methylglyoxal, 1, 2-dimethylglyoxal, and glyoxal

2. Methylglyoxal, 1, 3-dimethylglyoxal, and glyoxal

3. Methylglyoxal, 1, 4-dimethylglyoxal, and glyoxal

4. Methylglyoxal, 1, 5-dimethylglyoxal, and glyoxal

The correct order of decreasing reactivity of the following compounds:

Chlorobenzene, 2,4-Dinitrochlorobenzene, and p-Nitrochlorobenzene

with an electrophile (E⁺)  is :