The standard enthalpy of combustion at 25C of hydrogen, cyclohexene (C6H10), and cyclohexane (C6H12) are -241, -3800 and -3920 kJ mol-1, respectively. Calculate the standard enthalpy of hydrogenation of cyclohexene.

1. -131 kJ mol-1 2. -155 kJ mol-1
3. -167 kJ mol-1 4. -121 kJ mol-1
Subtopic:  Thermochemistry |
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The enthalpy of sublimation of a substance is equal to-

1. Enthalpy of fusion + Enthalpy of vaporisation

2. Enthalpy of fusion

3. Enthalpy of vaporisation

4.  Twice the enthalpy of vaporisation

Subtopic:  Thermochemistry |
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 N2 + 3 H2  2NH3 ; rH° = -92.4 kJ mol-1. The standard enthalpy of formation of NH3 gas in the above reaction would be-

1. -92.4 J (mol)-1 2. -46.2 kJ (mol)-1
3. +46.2 J (mol)-1 4. +92.4 kJ (mol)-1


Subtopic:  Thermochemistry |
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From the following bond energies:
H—H bond energy: 431.37 kJ mol-1 
C=C bond energy: 606.10 kJ mol-1 
C—C bond energy: 336.49 kJ mol-1 
C—H bond energy: 410.50 kJ mol-1 
Enthalpy for the reaction, 

will be:

1. 1523.6 kJ mol-1 2. -243.6 kJ mol-1
3. -120.0 kJ mol-1 4. 553.0 kJ mol-1
Subtopic:  Thermochemistry |
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Consider the following reaction,

S + O2  SO2,  H = – 298.2 kJ mole–1

SO2 + 1/2 O2   SO3H = – 98.7kJ mole–1

SO3 + H2 H2SO4H = – 130.2 kJ mole–1

H2 + 1/2 O2  H2O, H = – 287.3 kJ mole–1

the enthalpy of formation of H2SO4 at 298 K will be–

1. – 814.4 kJ mole–1 2. + 814.4 kJ mole–1
3. – 650.3 kJ mole–1 4. – 433.7 kJ mole–1
Subtopic:  Thermochemistry |
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Hf0 (298K) of methanol is given by the chemical equation -

1. C(diamond)+12O2+2H2CH3OH

2. CH4+12O2CH3OH

3. CO+2H2CH3OH

4. C(graphite)+12O2+2H2CH3OH

Subtopic:  Thermochemistry |
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Select the correct option based on statements given below:
Assertion (A): Combustion of all organic compounds is an exothermic reaction.
Reason (R): The enthalpies of all elements in their standard state are zero.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.
Subtopic:  Thermochemistry |
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The enthalpy of formation of COg, CO2g, N2Og , and N2O4g are

–110 kJ mol-1, – 393 kJ mol-1, 81 kJ mol-1, and 9.7 kJ mol-1 respectively.

The value of rH for the reaction would be-

N2O4g+3COgN2Og+3CO2g

1. -777.7 kJ mol-1
2.  +777.7 kJ mol-1
3.  +824.9 kJ mol-1
4. - 345.4 kJ mol-1

Subtopic:  Thermochemistry |
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The enthalpy of combustion of carbon to CO2 is –393.5 kJ mol-1. The amount of heat released upon formation of 35.2 g of CO2 from carbon and dioxygen gas would be-

1. -393.5 kJ mol-1

2. -314.8 kJ mol-1

3. +314.8 kJ mol-1

4. -320.5 kJ mol-1

Subtopic:  Thermochemistry |
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Which of the following is not an endothermic reaction?

1. Combustion of methane

2. Decomposition of water

3. Dehydrogenation of ethane or ethylene

4. Conversion of graphite to diamond

Subtopic:  Thermochemistry |
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