Select the correct option based on statements below:
Assertion (A): ∆H is positive for endothermic reactions.
Reason (R): If the total enthalpy of reactants and products are Hr & Hp respectively, then for an endothermic reaction
HR < HP.
 
1.  Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

Subtopic:  Enthalpy & Internal energy |
 77%
From NCERT
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Select the correct option based on statements below:
Assertion (A): Work done in an irreversible isothermal process at constant volume is zero.
Reason (R):  Work is assigned a negative sign during expansion and is assigned a positive sign during compression.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

Subtopic:  First Law of Thermodynamics |
 76%
From NCERT
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Select the correct option based on statements below:
Assertion (A):  Total enthalpy change of a multistep process is the sum of  ∆H1 + ∆H2 + ∆H3 + . . . . .
Reason (R):  When heat is absorbed by the system, the sign of q is taken to be negative.
 
1.  Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  First Law of Thermodynamics |
 78%
From NCERT
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Select the correct option based on statements below:
Assertion (A): Combustion is an exothermic process.
Reason (R): Combustion is a spontaneous process.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Thermochemistry |
 58%
From NCERT
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Select the correct option based on statements below:
Assertion (A): Dissolution of sugar in water proceeds via an increase in entropy.
Reason (R): Entropy decreases, when an egg is boiled hard.
  
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Spontaneity & Entropy |
 62%
From NCERT
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Select the correct option based on statements below:
Assertion (A):  Specific heat is an intensive property.
Reason (R):  Heat capacity is an extensive property.
 
1.  Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Classification of System, Extensive & Intensive Properties |
 71%
From NCERT
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Select the correct option based on statements below:
Assertion (A): Cdiamond → Cgraphite ∆H and  ∆U  are the same for this reaction.
Reason (R): Entropy increases during the conversion of diamond to graphite.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Enthalpy & Internal energy |
 63%
From NCERT
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For the given reaction 

2H2O2(l)  2H2O(l) + O2(g), the heat of formations of H2O2(l)  and H2O (l) are -188 kJ/mol & -286 KJ/mol respectively. The change in the enthalpy of the reaction will be:

1.  – 196 kJ/mol

2.  + 196 kJ/mol

3.  + 948 kJ/mol

4.  – 948 kJ/mol

Subtopic:  Enthalpy & Internal energy |
 74%
From NCERT
AIPMT - 2001
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For the reaction:

\(C_{3} H_{8} \left(\right. g \left.\right) + 5 O_{2} \left(\right. g \left.\right) \rightarrow 3 CO_{2} \left(\right. g \left.\right) + 4 H_{2} O \left(\right. l \left.\right)\) at constant temperature, ∆H – ∆E is:

1. + RT 2. – 3RT
3. + 3RT 4. – RT
Subtopic:  Enthalpy & Internal energy |
 83%
From NCERT
AIPMT - 2003
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At standard conditions, if the change in the enthalpy for the following reaction is –109 kJ mol
H2(g)+Br2(g)2HBr(g) and the bond energy of H2 and Br2 is 435 kJ mol–1 and 192 kJ mol–1 respectively, what is the bond energy (in kJ mol–1) of HBr?

1. 368 2. 736
3. 518 4. 259
Subtopic:  Thermochemistry |
 53%
From NCERT
NEET - 2020
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