Incorrect statement about peptide bond is:
 

1. C–N bond length in proteins is longer than the usual bond length of N-bond.
2. Spectroscopic analysis shows the planar structure of  group. 
3. C–N bond length in proteins is smaller than the usual bond length of the C–N bond.
4. None of the above.

Subtopic:  Hybridisation |
From NCERT
AIPMT - 2001
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Which of the following two species in the pair are isostructural:

1.  XeF2 , IF2-

2. NH3 , BF3

3.  CO3-2 , SO3-2

4. PCl5 , ICI5

Subtopic:  Octate, Isoelectronic Species, Lewis Structure & Formal Charge |
 85%
From NCERT
AIPMT - 2001
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The bond angle is maximum in:

1. NH3

2. NH4+

3. PCl3

4. SCl2

Subtopic:  Hybridisation |
 66%
From NCERT
AIPMT - 2001
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The incorrect statements among the following for sigma- and pi- bonds formed between two carbon atoms is:

1. Sigma-bond is stronger than a pi-bond
2. Bond energies of sigma- and pi-bonds are of the order of 264 KJ/mol and 347 KJ/mol, respectively
3. Free rotation of atoms about a sigma bond is allowed but not in the case of a pi-bond
4. Sigma-bond determines the direction between carbon atoms but a pi-bond has no primary effect in this regard
Subtopic:  Covalent Bond |
 68%
From NCERT
AIPMT - 2003
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If the main axis of a diatomic molecule is z, then the molecular orbital px and py overlap to form which of the following orbital:

1.  π molecular orbtial
2.  σ molecular orbital
3.  δ molecular orbtial
4.  No bond will form

Subtopic:  M.O.T |
From NCERT
AIPMT - 2001
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In NO3 ion, the number of bond pair and lone pair of electrons on nitrogen atom are respectively:

1. 2, 2 2. 3, 1
3. 1, 3 4. 4, 0
Subtopic:  Covalent Bond |
 68%
From NCERT
AIPMT - 2002
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 pπ-dπ bonding is present in:

1. NO3-

2. SO3-2

3. BO3-3

4. CO3-2

Subtopic:  Covalent Bond |
 86%
From NCERT
AIPMT - 2002
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Among the following, iso-electronic species are:

1. CO2, NO2

2. NO2-, CO2

3. CN, CO

4. SO2, CO2

Subtopic:  Octate, Isoelectronic Species, Lewis Structure & Formal Charge |
 84%
From NCERT
AIPMT - 2002
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The dipole moment of compound AB is 10.92 D and that of compound CD is 12.45 D. If the bond length of AB is 2.72 A° and that of CD is 2.56 A°, then for these compounds the correct statement is:
1.  More ionic nature in AB
2.  More ionic nature in CD
3.  Equal in both
4.  Cannot be predicted

Subtopic:  Polarity |
 74%
From NCERT
AIPMT - 1999
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The lone pairs in the BrF3 molecule, occupy equatorial positions to minimize:

1. Bond pair – bond pair repulsion only
2. Lone pair – lone pair repulsion and lone pair–bond pair repulsion
3. Lone pair–lone pair repulsion only
4. Lone pair–bond pair repulsion only
Subtopic:  V.S.E.P.R & V.B.T |
 75%
From NCERT
AIPMT - 2004
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