The possible values of n, l, and m for the electron present in 3d would be respectively:

1. n = 3, l = 1, m = – 2, – 1, 3, 1, 2

2. n = 3, l = 3, m = – 2, – 1, 0, 1, 2

3. n = 3, l = 2, m = – 2, – 1, 0, 1, 2

4. n = 5, l = 2, m = – 2, – 1, 0, 1, 2

The number of electrons that can be present in the subshells having m_s value of \(-\frac{1}{2}\) for n = 4 are:

1. 36

2. 4

3. 16

4. 2