Which of the following statements is not true for the rate constant, k?
 
1. large value of k indicates fast reactions.
2. The value of k is independent of the concentration of reactants
3. The value of k is independent of the concentration of products
4. The value of the rate constant, k, as the name suggests is always constant for a particular reaction at all temperatures.

 
Subtopic:  Arrhenius Equation |
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Level 2: 60%+
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दो कथन:
कथन (A): ऊष्माशोषी अभिक्रिया में अभिकारक की स्थितिज ऊर्जा उत्पाद से अधिक होती है।
कारण (R): अभिकारक सक्रिय संकुल बनाते हैं जिसकी ऊर्जा अभिकारक तथा उत्पाद दोनों से कम होती है।
 
1. (A) और (R) दोनों सत्य, (R) (A) की सही व्याख्या
2. दोनों सत्य, लेकिन (R) (A) की सही व्याख्या नहीं
3. (A) सत्य, (R) असत्य
4. दोनों असत्य
Subtopic:  Arrhenius Equation |
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The rate of a reaction is decreased by 3.555 times when the temperature was changed from 40°C to 30°C. The activation energy (in kJ mol-1) of the reaction is:
(Take R=8.314 J mol-1K-1 In 3.555=1.268)

1. 100 kJ/mol
2. 120 kJ/mol
3. 95 kJ/mol
4. 108 kJ/mol

Subtopic:  Arrhenius Equation |
Level 3: 35%-60%
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The rate constant, the activation energy and the Arrhenius parameter of a chemical reaction at \(25^{\circ}C\) are \(3\times10^{-4}~s^{-1},104.4~kJ~mol^{-1}\) and \(6\times10^{14}~s^{-1}\) respectively. The value of the rate constant as \(T\rightarrow\infty\) is

1.  \(2\times10^{18}~s^{-1}\)
2.  \(6\times10^{14}~s^{-1}\)
3.  \(\infty\)
4.  \(3.6\times10^{30}~s^{-1}\)
Subtopic:  Arrhenius Equation |
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What is the pre-exponential factor for a reaction at 500 K with a rate constant of 0.02 s⁻¹ and an activation energy of 18.230 kJ?


1. 1.61
2. 1.41
3. 1.81
4. 1.21
Subtopic:  Arrhenius Equation |
Level 3: 35%-60%
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