Mg(s) + 2Ag+(0.0001M)  Mg2+(0.130M) + 2Ag(s)

If  EƟ(cell) for the above mentioned cell is 3.17 V, then E(cell) value will be-

(log 13=1.1)

1. 2.87 V
2. 3.08 V
3. 2.96 V
4. 2.68 V

Subtopic:  Nernst Equation |
 53%
From NCERT
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Resistance of a conductivity cell filled with 0.1 mol L–1 KCl solution is 100 . If the resistance of the same cell when filled with 0.02 mol L–1 KCl solution is 520 . The conductivity of 0.1 mol L–1 KCl solution is 1.29 S/m. The molar conductivity of 0.02 mol L–1 KCl solution is-

1.
134 S cm2 mol–1
2. 124 S cm2 mol–1
3. 144 S cm2 mol–1
4. 154 S cm2 mol–1

Subtopic:  Conductance & Conductivity |
 76%
From NCERT
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Aluminium oxide may be electrolysed at 1000 °C to furnish aluminium metal.
The cathode reaction is  Al3+ + 3e- → Al.
To prepare 5.12 kg of aluminium metal by this method would require:
(Atomic mass = 27 amu; 1 faraday=96,500 Coulombs)

1. 5.49×101 C of electricity
2. 5.49×104 C of electricity
3. 1.83×107 C of electricity
4. 5.49×107 C of electricity

Subtopic:  Faraday’s Law of Electrolysis |
 62%
From NCERT
JEE
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Consider the following  reaction:

\(\frac{4}{3} \mathrm{Al}(\mathrm{s})+\mathrm{O}_2(\mathrm{~g}) \rightarrow \frac{2}{3} \mathrm{Al}_2 \mathrm{O}_3(\mathrm{~s})\), G=-827 KJ mol-1.
The minimum e.m.f. required to carry out the electrolysis of Al2O3 is:
(F = 96500 C mol–1)

1. 2.14 V

2. 4.28 V

3. 6.42 V

4. 8.56 V

Subtopic:  Electrode & Electrode Potential |
 67%
From NCERT
AIPMT - 2003
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The value of E0 cell for the following reaction is:
\(Cu^{2+}+ Sn^{2+}\to Cu +Sn^{4+ } \)

(Given, equilibrium constant is 106)

1. 0.17 2. 0.01
3. 0.05 4. 1.77
Subtopic:  Electrode & Electrode Potential |
 74%
From NCERT
AIPMT - 1999
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The potential of hydrogen electrode in contact with a solution with pH =10, is:

1. −0.0591 V 2. −5.91 V
3. 0.0591 V 4. −0.591 V
Subtopic:  Relation between Emf, G, Kc & pH |
 74%
From NCERT
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In a typical fuel cell, the reactants (R) and products (P) are: 

1. R = H2(g), O2(g); P = H2O2(l)
2. R = H2(g), O2(g); P = H2O(l)
3. R = H2(g), O2(g), C l2(g); P = HClO4(aq)
4. R = H2(g), N2(g); P = NH3(aq)

Subtopic:  Batteries & Salt Bridge |
 75%
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NEET - 2020
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The standard reduction potential of Zn2+/Zn  and Cu2+/Cu  is -0.76 and +0.34 V respectively. The oxidising agent and reducing agent, respectively, are 
1. Cu & Zn2+ 2. Zn & Cu
3. Cu2+ & Zn2+ 4. Cu2+ & Zn
Subtopic:  Electrochemical Series |
 67%
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Aqueous NaCl solution is electrolyzed using platinum electrodes. It can be concluded that the pH of the solution:
1. Increases  2. Decreases 
3. Unchanged  4. Can't be predicted 
Subtopic:  Electrolytic & Electrochemical Cell |
 68%
From NCERT
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Kohlrausch gives the following relation for strong electrolytes:
\(\wedge=\wedge_{0}-A \sqrt{C}\)
Which of the following equality holds?
\(\text { 1. } \Lambda=\Lambda_{0} \text { as } C \longrightarrow \sqrt{\Lambda}\)
\(\text { 2. } \Lambda=\Lambda_{0} \text { as } C \longrightarrow \infty\)
\(\text { 3. } \Lambda=\Lambda_{0} \text { as } \mathrm{C} \longrightarrow 0\)
\(\text { 4. } \Lambda=\Lambda_{0} \text { as } C \longrightarrow 1\)
Subtopic:  Conductance & Conductivity |  Kohlrausch Law & Cell Constant |
 69%
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