Number of geometrical isomer(s) possible for the complex [Cr(C2O4)3]3- is/are:
1. | 1 | 2. | 3 |
3. | 0 | 4. | 2 |
The correct statement among the following regarding \(FeCO_5\) is:
1. Tetranuclear
2. Mononuclear
3. Trinuclear
4. Dinuclear
The correct statements about ethane-1,2-diamine as a ligand are:
(a) | It is a neutral ligand |
(b) | It is a bidentate ligand |
(c) | It is a chelating ligand |
(d) | It is a unidentate ligand |
1. | a and b | 2. | b and c |
3. | a, b and c | 4. | a, c and d |
The correct electronic configuration of the central atom in based on crystal field theory is:
1. | \(e^4 ~t_{2 g}^2 \) | 2. | \(t_{2 g}^4 ~e_g^2 \) |
3. | \(t_{2 g}^6 ~e_g^0 \) | 4. | \(e^3 ~t^3_{2g}\) |
A metal ion present in vitamin B12 is:
1. | Fe(II) | 2. | Co(III) |
3. | Zn(II) | 4. | Ca(II) |
A complex has a molecular formula MSO4Cl.6H2O. Its aqueous solution gives white precipitate with barium chloride solution and no precipitate is obtained when it is treated with silver nitrate solution.
If the secondary valence of the metal is six, the correct representation of the complex is:
1. [M(H2O)4Cl]SO4.2H2O
2. [M(H2O)6]SO4
3. [M(H2O)5Cl]SO4.H2O
4. [M(H2O)3Cl]SO4.3H2O
The crystal field splitting energy is:
1. | The heat of formation between the two levels (e and t2) in tetrahedral splitting |
2. | The total pairing energy of the two levels (e and t2) in tetrahedral splitting. |
3. | The sum of the energy levels in an octahedral crystal field splitting. |
4. | The combined energy of the two levels (eg and t2g) in octahedral splitting. |
[Cr(NH3)6]3+ is paramagnetic ,while is diamagnetic because:
1. | Electrons in the 3d orbitals remain unpaired in |
2. | Electrons in the 3d orbitals remain unpaired in [Cr(NH3)6]3+ |
3. | Electrons in the 3p orbitals remain unpaired in [Cr(NH3)6]3+ |
4. | Electrons in the 3p orbitals remain unpaired in |
The correct splitting diagram of d orbitals in an octahedral crystal field is:
1. | 2. | ||
3. | 4. | None of these. |