Which of the following acids forms three series of salts?

1. H3PO2 2. H3BO3
3. H3PO4 4. H3PO3

Subtopic:  Ionisation Constant of Acid, Base & Salt |
 76%
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For the reaction N2O4(g) ⇌ 2NO2(g), the value of K(equilibrium constant) is 50 at 400 K and 1700 at 500 K. Which of the following option(s) is/are correct?

(a) The reaction is endothermic.
(b) The reaction is exothermic.
(c) If NO2(g) and N2O4(g) are mixed at 400 K at partial pressures 20 bar and 2 bar respectively, more N2O4(g)  will be formed.
(d) The entropy of the system increases.

1. (a, b, d)

2. (b, c, d)

3. (b, d, a)

4. (a, c, d)

Subtopic:  Kp, Kc & Factors Affecting them |
 77%
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What is the term used to define the temperature at which the solid and liquid phases of a pure substance can exist in equilibrium at a particular temperature and atmospheric pressure?

(a) Normal melting point

(b) Equilibrium temperature

(c) Boiling point

(d) Freezing point

Choose the correct option:

1. (a, b) 2. (b, c)
3. (c, d) 4. (a, d)
Subtopic:  Introduction To Equilibrium |
 52%
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The addition of a small amount of argon at a constant volume will not affect the equilibrium of the following reaction:

1. H2(g)+I2(g)⇌2HI(g)
2. PCl5(g)⇌ PCl3(g)+Cl2(g)
3. N2(g)+3H2(g)⇌2NH3(g)
4. The equilibrium will remain unaffected in all the three cases.

Subtopic:  Le Chatelier's principle |
 76%
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At 500 K, equilibrium constant, Kc, for the following reaction is 5.

12H2(g)+12I2(g)HI(g)

What would be the equilibrium constant Kc for the reaction?

2HI(g)H2(g)+I2(g)

1.  0.04

2.  0.4

3.  25

4.  2.5

Subtopic:  Kp, Kc & Factors Affecting them |
 80%
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On increasing the pressure, the direction in which the gas phase reaction proceeds to re-establish equilibrium is predicted by applying Le-Chatelier's principle. Consider the reaction,

N2(g)+3H2(g)2NH3(g)

Which of the following is correct, if the total pressure at which the equilibrium is established is increased without changing the temperature?

1. K will remain the same.
2. K will decrease.
3. K will increase.
4. K will increase initially and then decrease, when pressure is very high.

Subtopic:  Le Chatelier's principle |
 66%
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Which of the following alternatives best describes the reaction A ⇌ B at its halfway point?
1. \(\Delta G^{\ominus}=0\)
2. \(\Delta G^{\ominus}>0\)
3. \(\Delta G^{\ominus}<0\)
4. \(\Delta G^{\ominus}=-RTlnK\)

Subtopic:  Kp, Kc & Factors Affecting them |
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Ka for CH3COOH is 1.8×10-5 and Kb for NH4OH is 1.8×10-5. The pH of ammonium acetate will be: 

1. 7.005

2. 4.75

3. 7.0

4. Between 6 and 7

Subtopic:  Salt Hydrolysis & Titration |
 80%
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The value of the pH of \(0.01 \) \(\text{mol dm}^{-3}   \)\(\text{CH}_3\text{COOH}\) \(\left(K_a=1.74 \times 10^{-5}\right)\)  is:

1. 3.4 2. 3.6
3. 3.9 4. 3.0
Subtopic:  pH calculation |
 63%
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Among the following solvents, silver chloride is most soluble in:

1. \(0.1 \mathrm{~mol} ~\mathrm{dm}^{-3}~ \mathrm{AgNO}_3 \text { solution }\)
2. \(0.1 \mathrm{~mol} ~\mathrm{dm}^{-3}~ \mathrm{HCl} \text { solution }\)
3. \(\mathrm{H}_2 \mathrm{O}\)
4. Aqueous ammonia
Subtopic:  Common Ion Effect |
 52%
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