Ethylene diaminetetraacetate (EDTA) ion is:

1. Bidentate ligand with two "N" donor atoms
2. Tridentate ligand with three "N" donor atoms
3. Hexadentate ligand with four "O" and two "N'' donor atoms
4. Unidentate ligand
Subtopic:  Ligands |
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Which of the following is the correct order of increasing field strength of ligands?

1. SCNFCNC2O42-

2. FSCNC2O42CN-

3. CNC2O42SCNF-

4. SCNFC2O42CN-

Subtopic:  Ligands |
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What is the correct electronic configuration of the central atom in K4FeCN6 based on crystal field theory?

1.  e4 t2g  2

2.  t2g  4 eg2

3.  t2g  6 eg0

4.  e3 t2g 3

Subtopic:  VBT, CFT & their Limitations |
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The crystal field stabilization energy (CFSE) for [CoCl6]4 - is 18000 cm-1.    What will be the CFSE for [CoCl4]2-  

1. 6000 cm-1

2. 16000 cm-1

3. 18000 cm-1

4. 8000 cm-1

Subtopic:  VBT, CFT & their Limitations |
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The type of isomerism shown by the complex [CoCl2(en)2]+ is:
1. Geometrical isomerism
2. Coordination isomerism
3. Ionization isomerism
4. Linkage isomerism
Subtopic:  Isomerism in Coordination Compounds |
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The geometry and magnetic behaviour of the complex [Ni(CO)4] are

1. square planar geometry and diamagnetic
2. tetrahedral geometry and diamagnetic
3. square planar geometry and paramagnetic
4. tetrahedral geometry and paramagnetic

Subtopic:  VBT, CFT & their Limitations |
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Iron carbonyl, FeCO5 is:

1. Tetranuclear

2. Mononuclear

3. Trinuclear

4. Dinuclear

Subtopic:  Organometallic Complexes & their Uses |
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The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes:
CoCl3.6NH3, CoCl3.5NH3, CoCl3.4NH3 respectively is:

1. 3AgCl, 1AgCl, 2AgCl

2. 3AgCl, 2AgCl, 1AgCl

3. 2AgCl, 3AgCl, 1AgCl

4. 1AgCl, 3AgCl, 2AgCl

Subtopic:  Introduction, Classification and Nomenclature |
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What is the correct increasing order for the wavelengths of absorption in complexes of Co3+?

1. [Co(H2O)6]3+ < [Co(en)3]3+ < [Co(NH3)6]3 +

2. [Co(H2O)6]3+ <  [Co(NH3)6]3+ <  [Co(en)3]3+

3. [Co(NH3)6]3+ < [Co(en)3]3+ < [Co(H2O)6]3+

4. [Co(en)3]3+ <  [Co(NH3)6]3+ < [Co(H2O)6]3+

Subtopic:  VBT, CFT & their Limitations |
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Pick out the correct statement with respect to [Mn(CN)6]3-

1. It is sp3d2 hybridised and tetrahedral

2. It is d2sp3 hybridised and octahedral

3. It is dsp2 hybridised and square planar

4. It is sp3d2 hybridised and octahedral

Subtopic:  VBT, CFT & their Limitations |
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